Reaction of an aza[60]fullerene radical with diphenylmethanes and fluorenes: A mechanistic approach

被引：9

作者：

Vougioukalakis, GC ^{[1
]}

Hatzimarinaki, M ^{[1
]}

Lykakis, IN ^{[1
]}

Orfanopoulos, M ^{[1
]}

机构：

[1] Univ Crete, Dept Chem, GR-71409 Iraklion, Crete, Greece

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 71卷 / 02期

关键词：

D O I：

10.1021/jo051838d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The mechanism of the reaction of azafullerene radical C59N center dot with diphenylmethane and 9-methyl-9H-fluorene has been investigated. The primary and secondary kinetic isotope effects provide strong evidence for a stepwise mechanism in which the hydrogen-atom abstraction is the rate-determining step.

引用

页码：829 / 832

页数：4

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