Reaction of an aza[60]fullerene radical with diphenylmethanes and fluorenes: A mechanistic approach

被引：9
|
作者：
Vougioukalakis, GC [1 ]
Hatzimarinaki, M [1 ]
Lykakis, IN [1 ]
Orfanopoulos, M [1 ]
机构：
[1] Univ Crete, Dept Chem, GR-71409 Iraklion, Crete, Greece
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 71卷 / 02期
关键词：
D O I：
10.1021/jo051838d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] The mechanism of the reaction of azafullerene radical C59N center dot with diphenylmethane and 9-methyl-9H-fluorene has been investigated. The primary and secondary kinetic isotope effects provide strong evidence for a stepwise mechanism in which the hydrogen-atom abstraction is the rate-determining step.
引用
收藏
页码：829 / 832
页数：4
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