Influence of Nanoscale Morphology on Performance of Inverted Structure Metallated Conjugated Polymer Solar Cells

被引：3

作者：

Mohammad, Lal ^{[1
]}

Abu Mitul ^{[1
]}

Wang, Qi ^{[1
]}

Venkatesan, Swaminathan ^{[1
]}

Khatiwada, Devendra ^{[1
]}

Dubey, Ashish ^{[1
]}

Ho, Cheuk-Lam ^{[2
]}

Wong, Wai-Yeung ^{[2
]}

Qiao, Qiquan ^{[1
]}

机构：

[1] S Dakota State Univ, Dept Elect Engn, Ctr Adv Photovolta, Brookings, SD 57006 USA

[2] Hong Kong Baptist Univ, Inst Adv Mat, Dept Chem, Hong Kong, Hong Kong, Peoples R China

来源：

IEEE TRANSACTIONS ON ELECTRON DEVICES | 2015年 / 62卷 / 09期

基金：

美国国家科学基金会;

关键词：

Inverted structure; metallated conjugated polymers; nanoscale morphology; polymer solar cells (PSCs); ORGANIC TANDEM; METALLOPOLYMERS; EVOLUTION; BLENDS;

D O I：

10.1109/TED.2015.2455060

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

Inverted polymer solar cells (iPSCs) have shown a great potential in organic photovoltaics due to its enhanced stability and large-scale roll-to-roll processing. Metallated conjugated polymers also show promise as a donor material in the PSCs. In this paper, the role of solvents on the performance of inverted structure metallated PSCs was understood. Chlorobenzene (CB) and toluene were used as solvents to obtain the optimum morphology for improved device efficiency. To understand the charge transport properties and charge carrier lifetime in metallated polymer iPSCs, atomic force microscopy and transient photocurrent measurements were performed. The results showed that the CB as a solvent can improve the morphology of the active layer and enhance the performance of metallated iPSCs.

引用

页码：3029 / 3033

页数：5

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