RAMAN SPECTROSCOPY OF GeSe AND AgGeSe THIN FILMS

被引:0
|
作者
Conde Garrido, J. M. [1 ]
Piarristeguy, A. [2 ]
Le Parc, R. [3 ]
Urena, M. A. [1 ]
Fontana, M. [1 ]
Arcondo, B. [1 ]
Pradel, A. [2 ]
机构
[1] Univ Buenos Aires, CONICET, Fac Ingn, Lab Solidos Amorfos,INTECIN, RA-1063 Buenos Aires, DF, Argentina
[2] Univ Montpellier 2, Equipe PMDP CC3, ICG, UMR CNRS UM ENSCM UM1 5253 2 UM1, F-34095 Montpellier 5, France
[3] Univ Montpellier 2, UMR 5587, Lab Charles Coulomb, F-34095 Montpellier 5, France
来源
CHALCOGENIDE LETTERS | 2013年 / 10卷 / 11期
关键词
CHALCOGENIDE GLASSES; SE GLASSES; BULK GLASSES; AG; MODEL;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The structural properties of Ag-y(Ge0.25Se0.75)(1-y) thin films (y=0, 0.07, 0.10, 0.15, 0.20 and 0.25 at. fraction) were studied. The films were prepared by pulsed laser deposition using bulk glass targets of the studied ternary system and deposited onto microscope slides. Their amorphous structures were confirmed by XRD (X-ray Diffraction). The effect of silver content on films structures was analysed by Raman spectroscopy. Typical Raman vibration modes were observed in the Ge0.25Se0.75 binary film: Ge-Se corner-sharing tetrahedra mode (CS) at 199 cm(-1), edge sharing tetrahedra mode (ES) at 217 cm(-1), and Se-Se rings and chains mode at 255-265 cm(-1) (CM). In the Agy(Ge0.25Se0.75)(1-y) ternary thin films, the same modes were observed but with a red shift and an intensity reduction in the ES and CM bands.
引用
收藏
页码:427 / 433
页数:7
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