Oxaziridine-mediated amination of branched allylic sulfides: Stereospecific formation of allylic amine derivatives via [2,3]-sigmatropic rearrangement

被引：31
|
作者：
Armstrong, A [1 ]
Challinor, L
Cooke, RS
Moir, JH
Treweeke, NR
机构：
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England
[2] Organon Newhouse, Newhouse ML1 5SH, Lanark, Scotland
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 71卷 / 10期
关键词：
D O I：
10.1021/jo060369s
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Reaction of branched allylic sulfides with the N-Boc-oxaziridine 1 results in [2,3]-sigmatropic rearrangement of the intermediate allylic N-Boc-sulfimides with a high level of chirality transfer. The first example of formation of a quaternary stereocenter using this transformation is reported.
引用
收藏
页码：4028 / 4030
页数：3
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