Generation of 6H-benzo[f] cyclopenta[d][1,2] thiazepine 5,5-dioxides via a palladium-catalyzed reaction of 2-(2-alkynyl) benzenesulfonamide

被引：8
|
作者：
Wang, Huanhuan [1 ]
Luo, Yong [1 ]
Hou, Xiufeng [1 ]
Wu, Jie [1 ,2 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
DALTON TRANSACTIONS | 2013年 / 42卷 / 13期
基金：
中国国家自然科学基金;
关键词：
DIVERSITY-ORIENTED SYNTHESIS; ORGANIC-SYNTHESIS; 3-COMPONENT REACTION; DESIGN; 2-ALKYNYLANILINE; CYCLIZATIONS; CHEMISTRY; DISCOVERY; ACTIVATOR; SWITCHES;
D O I：
10.1039/c2dt32452k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An efficient approach for the assembly of 6H-benzo[f] cyclopenta[d][ 1,2] thiazepine 5,5-dioxides via a palladium-catalyzed tandem reaction of 2-(2-alkynyl) benzenesulfonamide with 2-alkynylvinyl bromide is reported. This transformation proceeds smoothly through a double carbopalladation with high efficiency.
引用
收藏
页码：4410 / 4415
页数：6
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