A luminescent iridium(III) cyclometallated complex immobilized in a polymeric matrix as a solid-state oxygen sensor

被引:61
|
作者
DiMarco, G [1 ]
Lanza, M [1 ]
Pieruccini, M [1 ]
Campagna, S [1 ]
机构
[1] UNIV MESSINA,DIPARTIMENTO CHIM INORGAN,I-98166 MESSINA,ITALY
关键词
D O I
10.1002/adma.19960080709
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Communication: In luminescence-based oxygen sensors the active luminescent species is usually a transition metal complex immobilized in a polymeric matrix-in most cases a ruthenium(II) polypyridine complex. In an attempt to overcome some of the disadvantages of these systems, a polymer-immobilized iridium(III) complex has been prepared and used for the first time as the active species in such a sensor. The luminescence properties of this system are described and its drawbacks with regard to sensors technology discussed.
引用
收藏
页码:576 / &
页数:6
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