catena-Poly[[(diethyl ether-κO)lithium(I)]-μ-1,1,3,3-tetraisopropyltriphosphane-κP2:κ2P1,P3-lithium(I)-μ-1,1,3,3-tetraisopropyltriphosphane-κ2P1,P3:κP2]

被引:1
|
作者
Domanska, W [1 ]
Chojnacki, J [1 ]
Pikies, J [1 ]
机构
[1] Gdansk Tech Univ, Dept Chem, PL-80952 Gdansk, Poland
关键词
D O I
10.1107/S1600536805043163
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Li-2(C12H28P3)(2)(C4H10O)](n), is a byproduct of the reaction of [(Et2PhP)2PtCl(2)] with (Pr2P)-Pr-i-P( SiMe3) Li in tetrahydrofuran. It is the second coordination polymer among known triphosphane-lithium salts. Of the two independent Li atoms, one is tetrahedrally coordinated, whereas the second has a trigonal environment.
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页码:M233 / M234
页数:2
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