Synthesis of 4,4′-dinonyl-2,2′-bithiazole-based copolymers via Pd-catalyzed direct C-H arylation

被引：59
|
作者：
Lu, Wei [1 ]
Kuwabara, Junpei [1 ]
Kanbara, Takaki [1 ]
机构：
[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba Res Ctr Interdisciplinary Mat Sci TIMS, Tsukuba, Ibaraki 3058573, Japan
来源：
POLYMER CHEMISTRY | 2012年 / 3卷 / 12期
关键词：
PI-CONJUGATED POLYMERS; METALATION-DEPROTONATION MECHANISM; POLYCONDENSATION; POLYMERIZATION; UNITS;
D O I：
10.1039/c2py20539d
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Direct arylation polycondensation of a bithiazole derivative with dibromoarylenes gave the corresponding bithiazole-based copolymers using the phosphine-free catalytic system in a short reaction time.
引用
收藏
页码：3217 / 3219
页数：3
相关论文
共 50 条
  • [41] A new and direct route to 3-fluoromethyl substituted pyrazol-4-acrylates via Pd-catalyzed C-H activation
    Wang, Xiaoguang
    Fang, Xiang
    Xiao, Hongyuan
    Gong, Dongming
    Yang, Xueyan
    Wu, Fanhong
    TETRAHEDRON, 2013, 69 (34) : 6993 - 7000
  • [42] Synthesis of Symmetrical 2,2',4,4'-Tetrasubstituted [4,4'-Bithiazole]-5,5'(4H,4'H)-diones and Their Reactions with Some Nucleophiles
    Andersen, K. K.
    Bray, D. D.
    Kjaer, A.
    Lin, Y.
    1997, (51):
  • [43] Synthesis of symmetrical 2,2',4,4'-tetrasubstituted [4,4'-bithiazole]-5,5'(4H,4'H)-diones and their reactions with some nucleophiles
    Andersen, KK
    Bray, DD
    Kjaer, A
    Lin, YH
    Shoja, M
    ACTA CHEMICA SCANDINAVICA, 1997, 51 (10): : 1000 - 1015
  • [44] Pd-catalyzed enantioselective C-H arylation of phosphinamides with boronic acids for the synthesis of P-stereogenic compounds
    Chen, Yuan-Hui
    Qin, Xu-Long
    Guan, Jing
    Du, Zhi-Jun
    Han, Fu-She
    TETRAHEDRON-ASYMMETRY, 2017, 28 (04) : 522 - 531
  • [45] Three-Step Synthesis of Fluoranthenes through Pd-Catalyzed Inter- and Intramolecular C-H Arylation
    Yamaguchi, Miyuki
    Higuchi, Mayu
    Tazawa, Kanae
    Manabe, Kei
    JOURNAL OF ORGANIC CHEMISTRY, 2016, 81 (09): : 3967 - 3974
  • [46] Synthesis of Unsymmetrical o-Biphenols and o-Binaphthols via Silicon-Tethered Pd-Catalyzed C-H Arylation
    Huang, Chunhui
    Gevorgyan, Vladimir
    ORGANIC LETTERS, 2010, 12 (10) : 2442 - 2445
  • [47] Synthesis of Indole-Derived Allocolchicine Congeners through Pd-Catalyzed Intramolecular C-H Arylation Reaction
    Sitnikov, Nikolay S.
    Kokisheva, Antonina S.
    Fukin, Georgy K.
    Neudoerfl, Joerg-Martin
    Sutorius, Hannah
    Prokop, Aram
    Fokin, Valery V.
    Schmalz, Hans-Guenther
    Fedorov, Alexey Yu
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2014, 2014 (29) : 6481 - 6492
  • [48] Synthesis and properties of fluorinated benzotriazole-based donor-acceptor-type conjugated polymers via Pd-catalyzed direct C-H/C-H coupling polymerization
    Li, Jingwen
    Han, Dong
    Zhang, Qiang
    He, Zewang
    Lu, Yan
    JOURNAL OF POLYMER SCIENCE, 2021, 59 (03) : 240 - 250
  • [49] Synthesis of condensed pyrroloindoles via Pd-catalyzed intramolecular C-H bond functionalization of pyrroles
    Seung, Jun Hwang
    Seung, Hwan Cho
    Chang, Sukbok
    Journal of the American Chemical Society, 2008, 130 (48): : 16158 - 16159
  • [50] Synthesis of Condensed Pyrroloindoles via Pd-Catalyzed Intramolecular C-H Bond Functionalization of Pyrroles
    Hwang, Seung Jun
    Cho, Seung Hwan
    Chang, Sukbok
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (48) : 16158 - +
12345