Manufacturing Macroporous Monoliths of Microporous Metal-Organic Frameworks

被引：30

作者：

Widmer, Remo N. ^{[1
]}

Lampronti, Giulio I. ^{[1
]}

Kunz, Benjamin ^{[2
]}

Battaglia, Corsin ^{[2
]}

Shepherd, Jennifer H. ^{[3
]}

Redfern, Simon A. T. ^{[1
]}

Bennett, Thomas D. ^{[3
]}

机构：

[1] Univ Cambridge, Dept Earth Sci, Downing St, Cambridge CB2 3EQ, England

[2] Empa, Swiss Fed Labs Mat Sci & Technol, Ueberlandstr 129, CH-8600 Dubendorf, Switzerland

[3] Univ Cambridge, Dept Mat Sci & Met, 27 Charles Babbage Rd, Cambridge CB3 0FS, England

来源：

ACS APPLIED NANO MATERIALS | 2018年 / 1卷 / 02期

基金：

英国工程与自然科学研究理事会;

关键词：

metal-organic frameworks; zeolitic imidazolate frameworks; porosity; sintering; monoliths; AMORPHIZATION; SEPARATION; ADSORPTION;

D O I：

10.1021/acsanm.7b00335

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

We report the first use of a pressure-assisted sintering technique on metal organic framework powders, allowing for the fast production of crystalline macroporous monoliths. Mechanical and microstructural characterization of the monoliths is presented. The interconnected macroporosity of the compacts can be adjusted, providing an immense interface for gas solid interaction. The sintering technique is well-established and commercially available, allowing industrial scale-up of the process.

引用

页码：497 / 500

页数：7

共 50 条

[21] Two Supramolecular Microporous Metal-Organic Frameworks Templated by Keggin Polyoxometalates
Liu, Yujing
Lin, Xiaoling
Liu, Guiying
Ying, Jun
Tian, Aixiang
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2012, 22 (05) : 946 - 951
[22] Metal-organic macrocycles, metal-organic polyhedra and metal-organic frameworks
Prakash, M. Jaya
Lah, Myoung Soo
CHEMICAL COMMUNICATIONS, 2009, (23) : 3326 - 3341
[23] Lanthanide metal-organic frameworks as selective microporous materials for adsorption of heavy metal ions
Jamali, Abbas
Tehrani, Alireza Azhdari
Shemirani, Farzaneh
Morsali, Ali
DALTON TRANSACTIONS, 2016, 45 (22) : 9193 - 9200
[24] Metal-organic frameworks
James, SL
CHEMICAL SOCIETY REVIEWS, 2003, 32 (05) : 276 - 288
[25] Metal-organic frameworks
Birkett, Jim
CHEMICAL & ENGINEERING NEWS, 2017, 95 (30) : 2 - 2
[26] Manufacturing of metal-organic framework monoliths and their application in CO2 adsorption
Hong, Wan Yun
Perera, Semali P.
Burrows, Andrew D.
MICROPOROUS AND MESOPOROUS MATERIALS, 2015, 214 : 149 - 155
[27] Metal-organic framework gels and monoliths
Hou, Jingwei
Sapnik, Adam F.
Bennett, Thomas D.
CHEMICAL SCIENCE, 2020, 11 (02) : 310 - 323
[28] Metal-Organic Frameworks and Metal-Organic Cages - A Perspective
Pilgrim, Ben S.
Champness, Neil R.
CHEMPLUSCHEM, 2020, 85 (08): : 1842 - 1856
[29] Structure, luminescence, and adsorption properties of two chiral microporous metal-organic frameworks
Fang, QR
Zhu, GS
Xue, M
Sun, JY
Sun, FX
Qiu, SL
INORGANIC CHEMISTRY, 2006, 45 (09) : 3582 - 3587
[30] Recent advances in microporous metal-organic frameworks as promising adsorbents for gas separation
Wang, Jia-Xin
Liang, Cong-Cong
Gu, Xiao-Wen
Wen, Hui-Min
Jiang, Chenghao
Li, Bin
Qian, Guodong
Chen, Banglin
JOURNAL OF MATERIALS CHEMISTRY A, 2022, 10 (35) : 17878 - 17916

← 1 2 3 4 5 →