Thermochemistry of the pyridinium- and pyrrolidinium-based ionic liquids

被引：14

作者：

Verevkin, Sergey P. ^{[1
,2
]}

Ralys, Ricardas V. ^{[1
]}

Emel'yanenko, Vladimir N. ^{[1
]}

Zaitsau, Dzmitry H. ^{[1
]}

Schick, Christoph ^{[2
,3
]}

机构：

[1] Univ Rostock, Dept Phys Chem, D-18059 Rostock, Germany

[2] Univ Rostock, Dept Life Light & Matter, Fac Interdisciplinary Res, D-18059 Rostock, Germany

[3] Univ Rostock, Dept Phys, D-18057 Rostock, Germany

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2013年 / 112卷 / 01期

关键词：

Ionic liquids; Differential scanning calorimetry; First-principles calculations; Enthalpy of reaction; Enthalpy of formation; Enthalpy of vaporization; COMBUSTION CALORIMETRY; VAPORIZATION; HEATS; PRESSURE; ENTHALPY;

D O I：

10.1007/s10973-012-2725-4

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

We applied DSC for the determination of enthalpies of synthesis reactions of pyridinium- and pyrrolidinium-based ionic liquids (ILs) from pyridine (or N-methyl-pyrrolidine) and n-alkyl bromides (with n = 4, 5, 6, 7, and 8). The combination of reaction enthalpy measurements by DSC with modern high-level first-principles calculations opens valuable indirect thermochemical options to obtain values of enthalpies of the formation and vaporization enthalpies of ILs.

引用

页码：353 / 358

页数：6

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