Copper-catalyzed intermolecular aminochlorination of alkenes

被引：20

作者：

Arteaga, Gean C. ^{[1
,2
]}

Saavedra-Olavarria, Jorge ^{[1
]}

Almendras, Sebastian ^{[1
]}

Hermosilla-Ibanez, Patricio ^{[3
]}

Almodovar, Iriux ^{[3
]}

Perez, Edwin G. ^{[1
]}

机构：

[1] Pontificia Univ Catolica Chile, Fac Chem, Dept Organ Chem, Av Vicuna Mackenna 4860,Casilla 306,Correo 22, Santiago, Chile

[2] Univ Sinu, Fac Ciencias & Ingn, Dept Ciencias Basicas, Cra 1w 38-153, Monteria, Colombia

[3] Univ Santiago Chile, USACh, Fac Quim & Biol, Santiago, Chile

来源：

TETRAHEDRON LETTERS | 2018年 / 59卷 / 12期

关键词：

Copper; Radical; Regioselective; Aminochlorination; Alkenes; N-FLUOROBENZENESULFONIMIDE; STYRENES; AMINOHALOGENATION; RECEPTORS; ALKYNES; BONDS;

D O I：

10.1016/j.tetlet.2018.02.010

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A copper-catalyzed radical and regioselective aminochlorination of alkenes using N-fluoro-benzenesulfonimide (NFSI) and TMSCl as nitrogen and chlorine sources respectively is reported. (C) 2018 Elsevier Ltd. All rights reserved.

引用

页码：1091 / 1093

页数：3

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