Copper-catalyzed intermolecular aminochlorination of alkenes

被引:20
|
作者
Arteaga, Gean C. [1 ,2 ]
Saavedra-Olavarria, Jorge [1 ]
Almendras, Sebastian [1 ]
Hermosilla-Ibanez, Patricio [3 ]
Almodovar, Iriux [3 ]
Perez, Edwin G. [1 ]
机构
[1] Pontificia Univ Catolica Chile, Fac Chem, Dept Organ Chem, Av Vicuna Mackenna 4860,Casilla 306,Correo 22, Santiago, Chile
[2] Univ Sinu, Fac Ciencias & Ingn, Dept Ciencias Basicas, Cra 1w 38-153, Monteria, Colombia
[3] Univ Santiago Chile, USACh, Fac Quim & Biol, Santiago, Chile
关键词
Copper; Radical; Regioselective; Aminochlorination; Alkenes; N-FLUOROBENZENESULFONIMIDE; STYRENES; AMINOHALOGENATION; RECEPTORS; ALKYNES; BONDS;
D O I
10.1016/j.tetlet.2018.02.010
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A copper-catalyzed radical and regioselective aminochlorination of alkenes using N-fluoro-benzenesulfonimide (NFSI) and TMSCl as nitrogen and chlorine sources respectively is reported. (C) 2018 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1091 / 1093
页数:3
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