A proton-conducting cesium sulfonate metal organic framework

被引：13

作者：

Wong, Norman ^{[1
]}

Hurd, Jeff A. ^{[1
]}

Vaidhyanathan, Ramanathan ^{[1
]}

Shimizu, George K. H. ^{[1
]}

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

来源：

CANADIAN JOURNAL OF CHEMISTRY | 2015年 / 93卷 / 09期

关键词：

metal organic framework; proton conduction; cesium; sulfonate; FUEL-CELL APPLICATIONS; ALKALI-METAL; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; DEGREES-C; MEMBRANES; WATER; ACID; HYDROGEN; EXCHANGE;

D O I：

10.1139/cjc-2014-0592

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a cesium sulfonate metal organic framework (Cs-3(L)(H2O)(3.3), 1, L = 1,3,5-trisulfonato-2,4,6-trihydroxybenzene) with hydrated channels that conduct protons at 1.1 x 10(-5) S cm(-1) at 50% relative humidity and 70 degrees C. Water was crystallographically observed in the structure, and the likely proton-transfer pathway was studied. The material was not robust, and appropriate parameters were employed to ensure meaningful data were extracted from the study.

引用

页码：988 / 991

页数：4

共 50 条

[41] One-step introduction of terminal sulfonic groups into a proton-conducting metal-organic framework by concerted deprotonation-metalation-hydrolysis reaction
Szufla, Monika
Roztocki, Kornel
Krawczuk, Anna
Matoga, Dariusz
DALTON TRANSACTIONS, 2020, 49 (29) : 9953 - 9956
[42] Li+ Ion-Conducting Sulfonate-Based Neutral Metal-Organic Framework
Panda, Dillip K.
Maity, Krishnendu
Palukoshka, Andrei
Ibrahim, Faysal
Saha, Sourav
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (05) : 4619 - 4624
[43] New frontiers of proton-conducting oxides
Medvedev, Dmitry
Shao, Zongping
CERAMICS INTERNATIONAL, 2024, 50 (20) : 40191 - 40191
[44] FUNCTIONING OF PROTON-CONDUCTING CHANNELS IN BIOMEMBRANES
TOMCHUK, PM
PROTSENKO, NA
KRASNOGOLOVETS, VV
BIOLOGICHESKIE MEMBRANY, 1984, 1 (11): : 1171 - 1178
[45] Composite proton-conducting membranes with nanodiamonds
Kulvelis, Yu. V.
Primachenko, O. N.
Odinokov, A. S.
Shvidchenko, A. V.
Bayramukov, V. Yu.
Gofman, I. V.
Lebedev, V. T.
Ivanchev, S. S.
Vul, A. Ya.
Kuklin, A. I.
Wu, B.
FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES, 2020, 28 (02) : 140 - 146
[46] NEW PROTON-CONDUCTING INORGANIC SOLIDS
CHOWDHRY, U
BARKLEY, JR
SLEIGHT, AW
AMERICAN CERAMIC SOCIETY BULLETIN, 1980, 59 (03): : 350 - 350
[47] Proton conducting behavior of a microporous metal-organic framework assisted by ligand isomerization
Liu, Houting
Lu, Jing
Liu, Zhiliang
Wang, Suna
Yan, Hui
Tian, Haiquan
JOURNAL OF SOLID STATE CHEMISTRY, 2020, 290
[48] pH-Dependent Proton Conducting Behavior in a Metal-Organic Framework Material
Phang, Won Ju
Lee, Woo Ram
Yoo, Kicheon
Ryu, Dae Won
Kim, BongSoo
Hong, Chang Seop
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (32) : 8383 - 8387
[49] Role of Framework-Carrier Interactions in Proton-Conducting Crystalline Porous Materials
Gupta, Arindam
Goswami, Soumyabrata
Elahi, Syed Meheboob
Konar, Sanjit
CRYSTAL GROWTH & DESIGN, 2021, 21 (03) : 1378 - 1388
[50] Fine morphology of proton-conducting ionomers
Ioselevich, AS
Kornyshev, AA
Steinke, JHG
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (32): : 11953 - 11963

← 1 2 3 4 5 →