Photoredox Catalysis with Metal Complexes Made from Earth-Abundant Elements

被引：292

作者：

Larsen, Christopher B. ^{[1
]}

Wenger, Oliver S. ^{[1
]}

机构：

[1] Univ Basel, Dept Chem, St Johanns Ring 19, CH-4056 Basel, Switzerland

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2018年 / 24卷 / 09期

基金：

瑞士国家科学基金会;

关键词：

electron transfer; energy transfer; photocatalysis; photochemistry; photophysics; TRANSFER RADICAL-ADDITION; CU-BASED SENSITIZERS; TERMINAL ALKYNES; ELECTRON-TRANSFER; CROSS-COUPLINGS; REGIOSELECTIVE SYNTHESIS; PHOTOCHEMICAL-SYNTHESIS; COPPER(I) COMPLEXES; IRON COMPLEXES; EXCITED-STATES;

D O I：

10.1002/chem.201703602

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photoredox chemistry with metal complexes as sensitizers and catalysts frequently relies on precious elements such as ruthenium or iridium. Over the past 5 years, important progress towards the use of complexes made from earth-abundant elements in photoredox catalysis has been made. This review summarizes the advances made with photoactive Cr-III, Fe-II, Cu-I, Zn-II, Zr-IV, Mo-0, and U-VI com-plexes in the context of synthetic organic photoredox chemistry using visible light as an energy input. Mechanistic considerations are combined with discussions of reaction types and scopes. Perspectives for the future of the field are discussed against the background of recent significant developments of new photoactive metal complexes made from earth-abundant elements.

引用

页码：2039 / +

页数：20

共 50 条

[31] Recent progress in electrochemical hydrogen production with earth-abundant metal complexes as catalysts
Wang, Mei
Chen, Lin
Sun, Licheng
ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (05) : 6763 - 6778
[32] Redox reactivity of LMCT and MLCT excited states of Earth-abundant metal complexes
Nam, Wonwoo
Lee, Yong-Min
Fukuzumi, Shunichi
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2024, 45 (06) : 503 - 519
[33] Emerging Earth-abundant (Fe, Co, Ni, Cu) molecular complexes for solar fuel catalysis
Sutra, P.
Igau, A.
CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY, 2018, 10 : 60 - 67
[34] Multiple morphologies and functionality of nanowires made from earth-abundant zinc phosphide
Steinvall, Simon Escobar
Tappy, Nicolas
Ghasemi, Masoomeh
Zamani, Reza R.
LaGrange, Thomas
Stutz, Elias Z.
Leran, Jean-Baptiste
Zamani, Mahdi
Paula, Rajrupa
Morral, Anna Fontcuberta i
NANOSCALE HORIZONS, 2020, 5 (02) : 274 - 282
[35] Earth-abundant Metal-catalyzed Reductive Amination: Recent Advances and Prospect for Future Catalysis
Liu, Jianguo
Song, Yanpei
Ma, Longlong
CHEMISTRY-AN ASIAN JOURNAL, 2021, 16 (17) : 2371 - 2391
[36] Chiral-at-Iron Catalyst: Expanding the Chemical Space for Asymmetric Earth-Abundant Metal Catalysis
Hong, Yubiao
Jarrige, Lucie
Harms, Klaus
Meggers, Eric
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (11) : 4569 - 4572
[37] Ligand imparts redox active character in earth-abundant metal complexes for multielectron processes
Ross, Dolores
Brazzolotto, Deborah
Borovik, Andrew
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
[38] Reaction: Earth-Abundant Metal Catalysts for Energy Conversions
Bullock, R. Morris
CHEM, 2017, 2 (04): : 444 - 446
[39] Earth-abundant elements a sustainable solution for electrocatalytic reduction of nitrate
Fajardo, Ana S.
Westerhoff, Paul
Sanchez-Sanchez, Carlos M.
Garcia-Segura, Sergi
APPLIED CATALYSIS B-ENVIRONMENTAL, 2021, 281 (281)
[40] Earth-abundant 3d transition metals on the rise in catalysis
Kaplaneris, Nikolaos
Ackermann, Lutz
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2022, 18 : 86 - 88

← 1 2 3 4 5 →