Photoredox Catalysis with Metal Complexes Made from Earth-Abundant Elements

被引：292
|
作者：
Larsen, Christopher B. [1 ]
Wenger, Oliver S. [1 ]
机构：
[1] Univ Basel, Dept Chem, St Johanns Ring 19, CH-4056 Basel, Switzerland
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2018年 / 24卷 / 09期
基金：
瑞士国家科学基金会;
关键词：
electron transfer; energy transfer; photocatalysis; photochemistry; photophysics; TRANSFER RADICAL-ADDITION; CU-BASED SENSITIZERS; TERMINAL ALKYNES; ELECTRON-TRANSFER; CROSS-COUPLINGS; REGIOSELECTIVE SYNTHESIS; PHOTOCHEMICAL-SYNTHESIS; COPPER(I) COMPLEXES; IRON COMPLEXES; EXCITED-STATES;
D O I：
10.1002/chem.201703602
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Photoredox chemistry with metal complexes as sensitizers and catalysts frequently relies on precious elements such as ruthenium or iridium. Over the past 5 years, important progress towards the use of complexes made from earth-abundant elements in photoredox catalysis has been made. This review summarizes the advances made with photoactive Cr-III, Fe-II, Cu-I, Zn-II, Zr-IV, Mo-0, and U-VI com-plexes in the context of synthetic organic photoredox chemistry using visible light as an energy input. Mechanistic considerations are combined with discussions of reaction types and scopes. Perspectives for the future of the field are discussed against the background of recent significant developments of new photoactive metal complexes made from earth-abundant elements.
引用
收藏
页码：2039 / +
页数：20
相关论文
共 50 条
  • [1] Photoredox catalysts based on earth-abundant metal complexes
    Hockin, Bryony M.
    Li, Chenfei
    Robertson, Neil
    Zysman-Colman, Eli
    CATALYSIS SCIENCE & TECHNOLOGY, 2019, 9 (04) : 889 - 915
  • [2] Earth-Abundant and Precious Metal Nanoparticle Catalysis
    Cortes-Clerget, Margery
    Akporji, Nnamdi
    Takale, Balaram S.
    Wood, Alex
    Landstrom, Evan
    Lipshutz, Bruce H.
    NANOPARTICLES IN CATALYSIS, 2020, 66 : 77 - 129
  • [3] Activation Strategies for Earth-Abundant Metal Catalysis
    Peng, Jingying
    Thomas, Stephen P.
    SYNLETT, 2020, 31 (12) : 1140 - 1146
  • [4] Visible-Light-Induced Homolysis of Earth-Abundant Metal-Substrate Complexes: A Complementary Activation Strategy in Photoredox Catalysis
    Abderrazak, Youssef
    Bhattacharyya, Aditya
    Reiser, Oliver
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (39) : 21100 - 21115
  • [5] Metal-organic layers for earth-abundant metal catalysis
    Lin, Zekai
    Lin, Wenbin
    Sawano, Takahiro
    Thacker, Nathan
    Wang, Cheng
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
  • [6] Earth-Abundant Metal Catalysis Enabled by Counterion Activation
    Agahi, Riaz
    Challinor, Amy J.
    Carter, Neil B.
    Thomas, Stephen P.
    ORGANIC LETTERS, 2019, 21 (04) : 993 - 997
  • [7] Synthesis of DBpin using Earth-abundant metal catalysis
    Cummins, Andrew W. M.
    Li, Shuyang
    Willcox, Dominic R.
    Muilu, Tommi
    Docherty, Jamie H.
    Thomas, Stephen P.
    TETRAHEDRON, 2020, 76 (15)
  • [8] Earth-Abundant Metals in Catalysis
    Ilies, Laurean
    Thomas, Stephen P.
    Tonks, Ian A.
    ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2020, 9 (03) : 324 - 325
  • [9] Metal-organic frameworks nodes for earth-abundant metal catalysis
    Ji, Pengfei
    Manna, Kuntal
    Lin, Zekai
    Lin, Wenbin
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
  • [10] Luminescent complexes made from chelating isocyanide ligands and earth-abundant metals
    Bueldt, Laura A.
    Wenger, Oliver S.
    DALTON TRANSACTIONS, 2017, 46 (44) : 15175 - 15177
12345