Study on Kinetics Behavior of PbO2/Pb(II) Couple in Graphite Felt Electrode

被引:0
|
作者
Bi, Xiaoguo [1 ]
Liu, Xudong [1 ]
Niu, Wei [1 ]
Dong, Yingnan [1 ]
机构
[1] Shenyang Inst Engn, Shenyang 110136, Peoples R China
来源
关键词
graphite felt; lead acid flow battery; PbO2/Pb(II) couple; cyclic voltammetry characteristics; SOLUBLE LEAD(II); FLOW BATTERY;
D O I
10.4028/www.scientific.net/AMR.550-553.1995
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This paper described the liquid flow battery system with graphite felt electrode and a single electrolyte, lead(II)in methanesulfonic acid. The kinetics and cyclic voltammetry behavior effects of PbO2/Pb(II) couple were studied. The results show that the equilibrium electrode potential PbO2/Pb(II) couple with good kinetics behavior was 1.21V. The cyclic voltammetry behavior of PbO2/Pb(II) couple on graphite felt electrode was studied, and the oxidization and reduction peak potentials were 1.547V and 1.241V, respectively. The graphite felt treated with sulfuric acid showed good electro-catalytic activity for PbO2/Pb(II) couple.
引用
收藏
页码:1995 / 1999
页数:5
相关论文
共 50 条
  • [41] Anodized graphite as an advanced substrate for electrodeposition of PbO2
    Abedini, Amin
    Valmoozi, Ali Asghar Ebrahimi
    Afghahi, Seyyed Salman Seyyed
    MATERIALS TODAY COMMUNICATIONS, 2022, 31
  • [42] Study of thermal behavior of α-PbO2, using TG and DSC
    Alamlhoda, A. A.
    Sajadi, S. A. A.
    Hashemian, S. J.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2008, 92 (03) : 917 - 920
  • [43] A ROTATING RING-DISC ELECTRODE STUDY OF THE FORMATION OF SOLUBLE PB (IV) SPECIES AT THE PBSO4/PBO2 ELECTRODE
    HAMEENOJA, E
    LAITINEN, T
    SUNDHOLM, G
    FINNISH CHEMICAL LETTERS, 1985, (3-4): : 173 - 173
  • [44] Study of thermal behavior of α-PbO2, using TG and DSC
    Sajadi S.A.A.
    Alamolhoda A.A.
    Hashemian S.J.
    Journal of Thermal Analysis and Calorimetry, 2008, 92 (3) : 917 - 920
  • [45] A POTENTIOSTATIC STUDY OF THE OXIDATION OF PBSO4 INTO PBO2 AT 3 ELECTRODE MATERIALS - PB AND PB-SB, PB-CA ALLOYS
    CHRAA, A
    CHEVALET, J
    CHEMLA, M
    DEGUIBERT, A
    JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1993, 90 (7-8) : 1541 - 1556
  • [46] Investigation of the Simultaneous Effect of Electrolyte Additives and α-PbO2 Intermediate Layer on the Electrodeposition of Ti/β-PbO2 Electrode
    Sharifidarabad, Hadi
    Zakeri, Alireza
    Adeli, Mandana
    IRANIAN JOURNAL OF MATERIALS SCIENCE AND ENGINEERING, 2024, 21 (03)
  • [47] Optimization of Operating Conditions for Electrochemical Decolorization of Methylene Blue with Ti/α-PbO2/β-PbO2 Composite Electrode
    Molla, Md. Ashraful Islam
    Yanagi, Genta
    Furukawa, Mai
    Tateishi, Ikki
    Katsumata, Hideyuki
    Kaneco, Satoshi
    JOURNAL OF COMPOSITES SCIENCE, 2021, 5 (05):
  • [48] Reaction and system modelling for Pb and PbO2 electrodes
    Varela, FE
    Codaro, EN
    Vilche, JR
    JOURNAL OF APPLIED ELECTROCHEMISTRY, 1997, 27 (11) : 1232 - 1244
  • [49] Reaction and system modelling for Pb and PbO2 electrodes
    F. E. VARELA
    E. N. CODARO
    J. R. VILCHE
    Journal of Applied Electrochemistry, 1997, 27 : 1232 - 1244
  • [50] Electrochemical oxidation of cinnamic acid with Mo modified PbO2 electrode: Electrode characterization, kinetics and degradation pathway
    Dai, Qizhou
    Zhou, Jiazhong
    Meng, Xiaoyang
    Feng, Daolun
    Wu, Chengqiang
    Chen, Jianmeng
    CHEMICAL ENGINEERING JOURNAL, 2016, 289 : 239 - 246