Zwitterionic copper(I) π-complexes:: Synthesis and crystal structure of [(CH2=CH-CH2)2NH2]Cu2Cl3

被引：0

作者：

Oliinik, VV ^{[1
]}

Glovyak, T

Mys'kiv, MG

机构：

[1] Ukrainian State Forestry Univ, Lviv, Ukraine

[2] Wroclaw B Beirut Univ, Inst Chem, PL-50383 Wroclaw, Poland

[3] Franko State Univ, UA-290005 Lviv, Ukraine

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 1999年 / 25卷 / 10期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystals of novel olefinic pi-complex [(CH2=CH-CH2)(2)NH2]Cu2Cl3 (I) were prepared by the ne electrochemical method. It was found (single-crystal KM-4 X-ray diffractometer, MoKalpha radiation, omega/2 theta scan mode) that I [space group P (1) over bar, a = 7.210(1), b = 7.4339(9), c = 10.093(2) Angstrom, alpha = 95.63(1)degrees, beta = 107.90(2)degrees, gamma = 91.95(1)degrees] is not isostructural with the previously studied [(CH2=CH-CH2)(2)NH2]Cu2Br3.

引用

页码：738 / 743

页数：6

共 50 条

[31] Crystal structure of iridium(III) complexes with ethylenediamine, K[Ir(NH2(CH2)2NH2)Cl 4] · 2H2O, and diimine, K[Ir(NH = CH-CH = NH)Cl4]
Koz'min, P.A.
Surazhskaya, M.D.
Golubnichaya, M.A.
Baranovskij, I.B.
Zhurnal Neorganicheskoj Khimii, 2003, 48 (02): : 276 - 281
[32] Copper(I) halide π-complexes with allylacetone azine.: Synthesis and crystal structure of 2CuX•CH2=CHCH2CH2C(CH3)=N-N=C(CH3)CH2CH2CH=CH2 (X = Cl-, Br-)
Filinchuk, YE
Mys'kiv, MG
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 1998, 24 (11) : 792 - 796
[33] Copper(I) Chloride and Bromide π-Complexes with the S-Allylisothiouronium Ligand: Synthesis and Crystal Structure of [CH2=CH-CH2-SC(=NH2)2]+CuX2-
Oliinik, V. V.
Schollmeyer, D.
Filinchuk, Ya. E.
Mys'kiv, M. G.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 1998, 24 (01) : 47 - 51
[34] Copper(I) chloride and bromide π-complexes with the s-allylisothiouronium ligand: synthesis and crystal structure of [CH2=CH-CH2-SC(=NH2)2]+CuX 2-
Oliinik, V.V.
Schollmeyer, D.
Filinchuk, Ya.E.
Mys'kiv, M.G.
Koordinatsionnaya Khimiya, 24 (01): : 52 - 57
[35] Copper(I) π-complexes with guanidine allyl derivatives:: Synthesis and crystal structures of [CH2=CH-CH2-NHC(=NH2)2]CuCl2-xBrx (x= 0.516) and [CH2=CH-CH2-NHC(=NH1)2]CuBr2
Filinchuk, YE
Mys'kiv, MG
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 1999, 25 (01) : 50 - 54
[36] Crystal structure of bis(triethylenetetramine) tris(zirconium) hexa(nitrilotriacetate) tetrahydrate, (NH3(CH2)2NH(CH2)2NH2(CH2)2NH3)2(Zr)3(N(CH2COO)3)6 • 4H2O
Haussühl, E
Haussühl, S
Schreuer, J
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2000, 215 (01): : 98 - 100
[37] Crystal structure of iridium(III) complexes with ethylenediamine, K[Ir(NH2(CH2)2NH2)Cl4] • 2H2O, and diimine, K[Ir(NH=CH-CH=NH)Cl4]
Koz'min, PA
Surazhskaya, MD
Golubnichaya, MA
Baranovskii, IB
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2003, 48 (02) : 224 - 227
[38] Solvothermal Synthesis and Crystal Structure of [H2N（CH2）2NH3]{Co[H2N（CH2）2NH2]3}[SbSe4]
FU Ming-Lai a
结构化学, 2004, (07) : 731 - 734
[39] Solvothermal synthesis and crystal structure of [H2N(CH2)2NH3]{CO[H2N(CH2)2NH2]3}[SbSe4]
Ming-Lai, F
Chen, WT
Cai, LZ
Liu, B
Guo, GC
Huang, JS
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (07) : 731 - 734
[40] STUDIES OF CHELATION-THERAPY - CRYSTAL AND MOLECULAR-STRUCTURE OF CU[H2N(CH2)2NH(CH2)3NH(CH2)2NH2](CIO4)2, CU(2,3,2-TET)(CIO4)2
FAWCETT, TG
RUDICH, SM
TOBY, BH
LALANCETTE, RA
POTENZA, JA
SCHUGAR, HJ
INORGANIC CHEMISTRY, 1980, 19 (04) : 940 - 945

← 1 2 3 4 5 →