Zwitterionic copper(I) π-complexes:: Synthesis and crystal structure of [(CH2=CH-CH2)2NH2]Cu2Cl3

被引:0
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作者
Oliinik, VV [1 ]
Glovyak, T
Mys'kiv, MG
机构
[1] Ukrainian State Forestry Univ, Lviv, Ukraine
[2] Wroclaw B Beirut Univ, Inst Chem, PL-50383 Wroclaw, Poland
[3] Franko State Univ, UA-290005 Lviv, Ukraine
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中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Crystals of novel olefinic pi-complex [(CH2=CH-CH2)(2)NH2]Cu2Cl3 (I) were prepared by the ne electrochemical method. It was found (single-crystal KM-4 X-ray diffractometer, MoKalpha radiation, omega/2 theta scan mode) that I [space group P (1) over bar, a = 7.210(1), b = 7.4339(9), c = 10.093(2) Angstrom, alpha = 95.63(1)degrees, beta = 107.90(2)degrees, gamma = 91.95(1)degrees] is not isostructural with the previously studied [(CH2=CH-CH2)(2)NH2]Cu2Br3.
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页码:738 / 743
页数:6
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