Zirconium-β Zeolite-Catalyzed Continuous-Flow Friedel-Crafts Acylation Reaction

被引：20
|
作者：
Rao, Xiaofeng [1 ]
Ishitani, Haruro [2 ]
Yoo, Woo-Jin [2 ]
Kobayashi, Shu [1 ,2 ]
机构：
[1] Univ Tokyo, Dept Chem, Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan
[2] Univ Tokyo, Grad Sch Sci, Green & Sustainable Chem Cooperat Lab, Bunkyo Ku, Tokyo 1130033, Japan
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 8卷 / 03期
基金：
日本科学技术振兴机构; 日本学术振兴会;
关键词：
acylation; zeolites; heterogeneous catalysis; continuous-flow; zirconium; H-BEA ZEOLITE; CHEMISTRY; ACID; OXIDATION; ANISOLE; HYDROGENATION; ALCOHOLS; KETONES; ACETYLATION; ALDEHYDES;
D O I：
10.1002/ajoc.201900012
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
H-beta Zeolites, doped with various metal salts, were investigated as heterogeneous catalysts for continuous-flow Friedel-Crafts acylation reactions. It was found that Zr-beta zeolites possessed excellent catalyst activity and stability, which enabled its use as a catalyst, up to 5 days, for Friedel-Crafts reactions between various activated arenes and acid anhydrides. Challenging substrates, such as toluene and m-xylene, were also successfully applied for the continuous-flow process.
引用
收藏
页码：316 / 319
页数：4
相关论文
共 50 条
  • [21] Application of zeolite molecular sieves in Friedel-Crafts acylation reactions
    Yuan, B
    Qiao, WH
    Li, ZS
    Wang, GR
    Cheng, LB
    PROGRESS IN CHEMISTRY, 2005, 17 (04) : 686 - 691
  • [22] Structures and reaction mechanisms of Friedel-Crafts acylation reactions over acid faujasite zeolite
    Yutthalekha, Thittaya
    Boekfa, Bundet
    Limtrakul, Jumras
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
  • [23] Acyl iodides in the reaction of photochemical Friedel-Crafts acylation
    Vlasova, N. N.
    Vlasov, A. V.
    Grigor'eva, O. Yu.
    Albanov, A. I.
    Voronkov, M. G.
    DOKLADY CHEMISTRY, 2010, 435 : 294 - 296
  • [24] THE DIPHENYLBORYL HEXACHLOROANTIMONATE PROMOTED FRIEDEL-CRAFTS ACYLATION REACTION
    MUKAIYAMA, T
    NAGAOKA, H
    OHSHIMA, M
    MURAKAMI, M
    CHEMISTRY LETTERS, 1986, (02) : 165 - 168
  • [25] Acyl iodides in the reaction of photochemical Friedel-Crafts acylation
    N. N. Vlasova
    A. V. Vlasov
    O. Yu. Grigor’eva
    A. I. Albanov
    M. G. Voronkov
    Doklady Chemistry, 2010, 435 : 294 - 296
  • [26] FRIEDEL-CRAFTS ACYLATION REACTION .4. MULTIPLE SUBSTITUENT EFFECT IN FRIEDEL-CRAFTS ACYLATION OF TOLUENE WITH DISUBSTITUTED BENZOYL CHLORIDES
    SLOOTMAEKERS, PJ
    VERBEERS.R
    BULLETIN DES SOCIETES CHIMIQUES BELGES, 1968, 77 (5-6): : 273 - +
  • [27] Trifluoromethanesulfonic acid catalyzed Friedel-Crafts acylation of aromatics with β-lactams
    Anderson, KW
    Tepe, JJ
    TETRAHEDRON, 2002, 58 (42) : 8475 - 8481
  • [28] Friedel-Crafts acylation and related reactions catalyzed by heteropoly acids
    Kaur, J
    Kozhevnikova, EF
    Griffin, K
    Harrison, B
    Kozhevnikov, IV
    KINETICS AND CATALYSIS, 2003, 44 (02) : 175 - 182
  • [29] Friedel-Crafts acylation of 2-methoxynaphthalene over zeolite catalysts
    Das, D
    Cheng, SF
    APPLIED CATALYSIS A-GENERAL, 2000, 201 (02) : 159 - 168
  • [30] EFFECT OF COMPONENTS AND REACTION CONDITIONS ON FRIEDEL-CRAFTS ACYLATION .2. FACTORS AFFECTING REACTIVITY OF AROMATIC COMPOUNDS IN FRIEDEL-CRAFTS ACYLATION
    BELENKII, LI
    YAKUBOV, AP
    GOLDFARB, YL
    ZHURNAL ORGANICHESKOI KHIMII, 1970, 6 (12): : 2524 - &
12345