Biphasic Hydroformylation of 1-Octene Catalyzed by Ionic Rh(III)-complex in the Presence of Tertiary Amine Functionalized Ionic Liquid

被引：0

作者：

Shi Dingfu ^{[1
]}

Tan Chen ^{[1
]}

Wang Peng ^{[1
]}

Li Yongqi ^{[1
]}

Chen Shengjie ^{[1
]}

Liu Ye ^{[1
]}

机构：

[1] E China Normal Univ, Sch Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2015年 / 36卷 / 08期

基金：

中国国家自然科学基金;

关键词：

Rh-complex; Functionalized ionic liquid; Hydroformylation; 1-Octene; Tertiary amine; PHOSPHINE; EFFICIENT; COMPLEX; LIGANDS;

D O I：

10.7503/cjcu20150221

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ionic Rh(III) -complexes la and 2a exhibited poor catalytic performance for hydroformylation of 1-octene without the presence of any auxiliary additive. The involvement of cheap and low-toxic tertiary amines such as Et3N or N-methylpiperidine could dramatically boost the catalytic performance of compounds la and 2a up to turnover frequency(TOF) of 800 h(-1). When piperidinyl-functionalized ionic liquid of [PEmim] BF4 was dually used as the additive and the solvent, not only the positive roles of N-methylpiperidine in spurring up the activity of compounds la and 2a were embodied, but also the easy recovery and recycling of compounds la(or 2a) in [PEmim] BF4 were fulfilled in biphasic hydroformylation. The TOFs of compounds la and 2a in [PEmin] BF4 were gradually decreased in the course of the recycling uses due to the leaching and deactivation of the catalysts.

引用

页码：1553 / 1558

页数：6

共 35 条

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