Biphasic Hydroformylation of 1-Octene Catalyzed by Ionic Rh(III)-complex in the Presence of Tertiary Amine Functionalized Ionic Liquid

被引：0
|
作者：
Shi Dingfu [1 ]
Tan Chen [1 ]
Wang Peng [1 ]
Li Yongqi [1 ]
Chen Shengjie [1 ]
Liu Ye [1 ]
机构：
[1] E China Normal Univ, Sch Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China
来源：
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2015年 / 36卷 / 08期
基金：
中国国家自然科学基金;
关键词：
Rh-complex; Functionalized ionic liquid; Hydroformylation; 1-Octene; Tertiary amine; PHOSPHINE; EFFICIENT; COMPLEX; LIGANDS;
D O I：
10.7503/cjcu20150221
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The ionic Rh(III) -complexes la and 2a exhibited poor catalytic performance for hydroformylation of 1-octene without the presence of any auxiliary additive. The involvement of cheap and low-toxic tertiary amines such as Et3N or N-methylpiperidine could dramatically boost the catalytic performance of compounds la and 2a up to turnover frequency(TOF) of 800 h(-1). When piperidinyl-functionalized ionic liquid of [PEmim] BF4 was dually used as the additive and the solvent, not only the positive roles of N-methylpiperidine in spurring up the activity of compounds la and 2a were embodied, but also the easy recovery and recycling of compounds la(or 2a) in [PEmim] BF4 were fulfilled in biphasic hydroformylation. The TOFs of compounds la and 2a in [PEmin] BF4 were gradually decreased in the course of the recycling uses due to the leaching and deactivation of the catalysts.
引用
收藏
页码：1553 / 1558
页数：6
相关论文
共 35 条
  • [1] Imidazoliophosphines are True N-Heterocyclic Carbene (NHC)-Phosphenium Adducts
    Abdellah, Ibrahim
    Lepetit, Christine
    Canac, Yves
    Duhayon, Carine
    Chauvin, Remi
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (44) : 13095 - 13108
  • [2] Ali B. E., 2005, J MOL CATAL A-CHEM, V230, P9
  • [3] Ali BassamEl., 2003, CATAL COMMUN, V4, P621
  • [4] Synthesis of New Cationic Donor-Stabilized Phosphenium Adducts and Their Unexpected P-Substituent Exchange Reactions
    Azouri, Michele
    Andrieu, Jacques
    Picquet, Michel
    Cattey, Helene
    [J]. INORGANIC CHEMISTRY, 2009, 48 (03) : 1236 - 1242
  • [5] SURFACE-ACTIVE PHOSPHINES FOR CATALYSIS UNDER 2-PHASE REACTION CONDITIONS - P(MENTHYL)[(CH2)(8)C6H4-P-SO3NA](2) AND THE HYDROFORMYLATION OF STYRENE
    BARTIK, T
    DING, H
    BARTIK, B
    HANSON, BE
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 98 (03) : 117 - 122
  • [6] CRYSTAL AND MOLECULAR-STRUCTURE OF ORANGE AND RED ALLOTROPES OF CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)
    BENNETT, MJ
    DONALDSON, PB
    [J]. INORGANIC CHEMISTRY, 1977, 16 (03) : 655 - 660
  • [7] Steric vs. electronic anomaly observed from iodomethane oxidative addition to tertiary phosphine modified rhodium(I) acetylacetonato complexes following progressive phenyl replacement by cyclohexyl [PR3 = PPh3, PPh2Cy, PPhCy2 and PCy3]
    Brink, Alice
    Roodt, Andreas
    Steyl, Gideon
    Visser, Hendrik G.
    [J]. DALTON TRANSACTIONS, 2010, 39 (23) : 5572 - 5578
  • [8] REACTIONS OF CATECHOLBORANE WITH WILKINSON CATALYST - IMPLICATIONS FOR TRANSITION METAL-CATALYZED HYDROBORATIONS OF ALKENES
    BURGESS, K
    VANDERDONK, WA
    WESTCOTT, SA
    MARDER, TB
    BAKER, RT
    CALABRESE, JC
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (24) : 9350 - 9359
  • [9] NHC-Derived Bis(amidiniophosphine) Ligands of Rh(l) Complexes: Versatile cis-trans Chelation Driven by an Interplay of Electrostatic and Orbital Effects
    Canac, Yves
    Debono, Nathalie
    Vendier, Laure
    Chauvin, Remi
    [J]. INORGANIC CHEMISTRY, 2009, 48 (12) : 5562 - 5568
  • [10] Ionic Rh(I)-complexes containing π-accepting and hemilabile P,N-ligands as efficient catalysts for hydroformylation of 1-octene
    Chen, Sheng-Jie
    Li, Yong-Qi
    Wang, Yong-Yong
    Zhao, Xiao-Li
    Liu, Ye
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2015, 396 : 68 - 76
1234