Ammonium bisulfate water equilibrium and metastability phase diagrams

被引：36

作者：

Imre, DG ^{[1
]}

Xu, J ^{[1
]}

Tang, IN ^{[1
]}

McGraw, R ^{[1
]}

机构：

[1] SUNY, INST TERR & PLANETARY ATMOSPHERES, NEW YORK, NY 11794 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 1997年 / 101卷 / 23期

关键词：

D O I：

10.1021/jp9704426

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Though ammonium bisulfate is one of the most common of atmospheric hygroscopic aerosols, knowledge of its interaction with water has, until now, been extremely limited. This paper presents our observations on single isolated ammonium bisulfate aerosol particles, as they interact with water vapor at temperatures ranging from -40 to 30 degrees C. The complete phase diagram in the temperature/composition as well as the pressure/temperature domains has been derived here for the first time, mapping out equilibrium and metastable to stable phase transitions. A new low-temperature crystalline hydrate phase that might have an important role in processes occurring in the upper troposphere has been discovered.

引用

页码：4191 / 4195

页数：5

共 50 条

[41] Structure of the phase equilibrium diagrams of aluminum alloys with scandium
L. L. Rokhlin
T. V. Dobatkina
M. L. Kharakterova
Powder Metallurgy and Metal Ceramics, 1997, 36 : 128 - 132
[42] A SIMPLE METHOD FOR THE CALCULATION OF EQUILIBRIUM PHASE-DIAGRAMS
LIN, L
WOLLANTS, P
VANDERBIEST, O
DELAEY, L
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 1994, 18 (01): : 89 - 98
[43] PHASE-EQUILIBRIUM DIAGRAMS AND LIQUID-STATE
WANG, FE
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 1978, 2 (03): : 239 - 278
[44] Construction of equilibrium phase diagrams: Some errors to be avoided
Laughlin, David E.
Massalski, T. B.
PROGRESS IN MATERIALS SCIENCE, 2021, 120
[45] COHERENT PHASE-EQUILIBRIUM AND STATE DIAGRAMS IN SOLIDS
ROITBURD, AL
FIZIKA TVERDOGO TELA, 1984, 26 (07): : 2025 - 2032
[46] THE TEMPERATURE COMPOSITION PHASE-DIAGRAM OF MONOMYRISTOLEIN IN WATER - EQUILIBRIUM AND METASTABILITY ASPECTS (VOL 66, PG 573, 1994)
BRIGGS, J
CAFFREY, M
BIOPHYSICAL JOURNAL, 1994, 66 (04) : 1263 - 1263
[47] On the Configuration of Closed Two-Phase Regions in Equilibrium Phase Diagrams
Evgeny, Sidorov
Mikhail, Pikunov
JOURNAL OF IRON AND STEEL RESEARCH INTERNATIONAL, 2009, 16 : 1212 - 1215
[48] COHERENT PHASE-EQUILIBRIUM AND PHASE-STABILITY DIAGRAMS IN SOLIDS
ROITBURD, AL
JOURNAL OF METALS, 1988, 40 (07): : A43 - A43
[49] SPECIFICATION OF THE CONFIGURATION OF TWO-PHASE REGIONS IN EQUILIBRIUM PHASE DIAGRAMS
Sidorov, Evgeny
Pikunov, Mikhail
METAL 2010: 19TH INTERNATIONAL METALLURGICAL AND MATERIALS CONFERENCE, 2010, : 753 - 756
[50] EXPERIMENTAL INVESTIGATION OF THE FERROELECTRIC PROPERTIES OF AMMONIUM BISULFATE IN THE VICINITY OF THE HIGH-TEMPERATURE PHASE TRANSITION
STRUKOV, BA
KOPTSIK, VA
LIGASOVA, VD
SOVIET PHYSICS-SOLID STATE, 1962, 4 (05): : 977 - 980

← 1 2 3 4 5 →