The cathodic electrochemiluminescence (ECL) behavior of Eosin Y (EY)-peroxydisulfate (S2O82-) system at a glassy carbon electrode (GCE) was studied under cyclic voltammetric conditions. Two strong ECL peaks, ECL-1 and ECL-2 were observed in cathodic and anodic scan process respectively under the potential scan range 0 to -2.0 V. The effects of pH value, S2O82- concentration on the ECL intensity were investigated and the possible mechanism for the ECL behavior of EY-S2O82- system was proposed. Based on the stable cathodic ECL of EY-S2O82- system and quenching effect of guanine on the ECL-1 and ECL-2 intensity simultaneously, the logarithmic plot of the inhibited ECL-1 and ECL-2 versus logarithmic plot of the concentration of guanine was linear over the range of 5.0 x 10(-6)-1.0 x 10(-4) mol/L with a correlation coefficient of 0.998 and 0.996, respectively. (c) 2012 Elsevier B.V. All rights reserved.
机构:
School of Chemistry and Chemical Engineering, Yan’an University, Yan’an,716000, China
Yan’an Key Laboratory of Analytical Technology and Detection, Yan’an,716000, ChinaSchool of Chemistry and Chemical Engineering, Yan’an University, Yan’an,716000, China
Shen, Yuman
Tian, Rui
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School of Chemistry and Chemical Engineering, Yan’an University, Yan’an,716000, China
Yan’an Key Laboratory of Analytical Technology and Detection, Yan’an,716000, ChinaSchool of Chemistry and Chemical Engineering, Yan’an University, Yan’an,716000, China
Tian, Rui
Gao, Chuan
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机构:
School of Chemistry and Chemical Engineering, Yan’an University, Yan’an,716000, China
Yan’an Key Laboratory of Analytical Technology and Detection, Yan’an,716000, ChinaSchool of Chemistry and Chemical Engineering, Yan’an University, Yan’an,716000, China
Gao, Chuan
Ma, Hongyan
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School of Chemistry and Chemical Engineering, Yan’an University, Yan’an,716000, China
Yan’an Key Laboratory of Analytical Technology and Detection, Yan’an,716000, ChinaSchool of Chemistry and Chemical Engineering, Yan’an University, Yan’an,716000, China
Ma, Hongyan
Zhang, Pan
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机构:
School of Chemistry and Chemical Engineering, Yan’an University, Yan’an,716000, China
Yan’an Key Laboratory of Analytical Technology and Detection, Yan’an,716000, ChinaSchool of Chemistry and Chemical Engineering, Yan’an University, Yan’an,716000, China