Cathodic electrochemiluminescence of Eosin Y-peroxydisulfate system and its analytical application for determination of guanine

被引:7
|
作者
Zhu, Yinggui [1 ]
Liu, Junying [1 ]
Chen, Kun [1 ]
Shu, Guibo [1 ]
Yang, Yu [1 ]
机构
[1] Anhui Normal Univ, Coll Chem & Mat Sci, Wuhu 241000, Peoples R China
基金
中国国家自然科学基金;
关键词
Cathodic electrochemiluminescence; Eosin Y; Peroxydisulfate; Guanine; PURELY AQUEOUS-SOLUTION; ELECTROGENERATED CHEMILUMINESCENCE; THIN-FILMS; RU(BPY)(3)(2+); NUCLEOSIDES; PERFORMANCE; ELECTRODES; COMPOSITE; BEHAVIOR;
D O I
10.1016/j.jelechem.2012.11.017
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The cathodic electrochemiluminescence (ECL) behavior of Eosin Y (EY)-peroxydisulfate (S2O82-) system at a glassy carbon electrode (GCE) was studied under cyclic voltammetric conditions. Two strong ECL peaks, ECL-1 and ECL-2 were observed in cathodic and anodic scan process respectively under the potential scan range 0 to -2.0 V. The effects of pH value, S2O82- concentration on the ECL intensity were investigated and the possible mechanism for the ECL behavior of EY-S2O82- system was proposed. Based on the stable cathodic ECL of EY-S2O82- system and quenching effect of guanine on the ECL-1 and ECL-2 intensity simultaneously, the logarithmic plot of the inhibited ECL-1 and ECL-2 versus logarithmic plot of the concentration of guanine was linear over the range of 5.0 x 10(-6)-1.0 x 10(-4) mol/L with a correlation coefficient of 0.998 and 0.996, respectively. (c) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:46 / 50
页数:5
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