Synthesis and luminescent properties of M2P2O7:Eu3+ (M = Ca, Sr, Ba) phosphors

被引:8
|
作者
Mo, Fuwang [1 ]
Wang, Rongfang [1 ]
Lan, Yuwei [1 ]
Zhou, Liya [1 ]
He, Tao [1 ]
Xu, Xianmei [1 ]
机构
[1] Guangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R China
关键词
phosphors; photoluminescence; X-ray diffraction; LIGHT-EMITTING-DIODES;
D O I
10.4028/www.scientific.net/AMR.399-401.978
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A series of orange-red phosphors M(2)P(2)o(7): Eu3+ (M = Ca, Sr, Ba) were prepared by traditional solid-state reaction method. X-ray diffraction analysis confirmed the formation of Ca2P2O7, Sr2P2O7 and Ba2P2O7. Scanning electron-microscopy observation indicated a narrow size-distribution of about 0.6 similar to 1 mu m for the particles with a quadrate shape. Photoluminescence spectra of M2P2O7(M = Ca, Sr, Ba): Eu3+ phosphors showed a strong excitation peak around 393 nm, and Ca2P2O7: Eu3+, Sr2P2O7: Eu3+ and Ba2P2O7: Eu3+ phosphors showed strong emission bands peaking at about 593 nm, which suggests that the Eu3+ ion is occupy the site with center of symmetry.
引用
收藏
页码:978 / 981
页数:4
相关论文
共 50 条
  • [41] Synthesis and Luminescent Properties of (Sr,M)2Si(O1-xNx)4:Eu2+ (M: Mg2+, Ca2+, Ba2+)
    Lee, Seung Jae
    Hong, Seong-Hyeon
    Kim, Young Jin
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2012, 159 (05) : J163 - J167
  • [42] VUV luminescence property of MAl2B2O7:Re(M = Sr, Ba, Ca; Re = Eu3+, Tb3+)
    Hou Tao
    He Dawei
    Li Xin
    Wang Yongsehng
    RARE METAL MATERIALS AND ENGINEERING, 2007, 36 : 422 - 425
  • [43] Matrix-induced synthesis and photoluminescence of M2RENbO6: Eu3+ (M = Ca, Sr, Ba; RE = Y, Gd, La) phosphors by hybrid precursors
    Xiao, Xiu Zhen
    Yan, Bing
    JOURNAL OF ALLOYS AND COMPOUNDS, 2007, 433 (1-2) : 246 - 250
  • [44] Preparation and characterization of long afterglow M2MgSi2O7-based (M: Ca, Sr, Ba) photoluminescent phosphors
    Lin, YH
    Nan, CW
    Zhou, XS
    Wu, JB
    Wang, HF
    Chen, DP
    Xu, SM
    MATERIALS CHEMISTRY AND PHYSICS, 2003, 82 (03) : 860 - 863
  • [45] Luminescence properties of M2MgSi2O7: Re (M = Ba, Sr, Ca) (Re = Eu2+, Ce3+, Tb3+)
    He, Dawei
    Shi, Yanning
    Hou, Tao
    Zhou, Dan
    HIGH-PERFORMANCE CERAMICS IV, PTS 1-3, 2007, 336-338 : 622 - +
  • [46] Preparation method and luminescent properties of Ca7-x,SrxSi2P2O16:Eu3+ red-emitting phosphors
    Li, Junfeng
    Cao, Wenqiang
    Liu, Yuqing
    Gao, Yang
    Zhang, Wentao
    Zhang, Peicong
    JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 2017, 19 (1-2): : 33 - 37
  • [47] Synthesis and luminescent properties of Y6W2O15:Eu3+ phosphors
    Huang, Jinping
    Luo, Hongshan
    Zhou, Pingle
    Yu, Xibin
    Li, Yikang
    JOURNAL OF LUMINESCENCE, 2007, 126 (02) : 881 - 885
  • [48] Synthesis and luminescence properties of glass ceramics containing MSiO3:Eu2+ (M=Ca, Sr, Ba) phosphors for white LED
    Cui, Zhiguang
    Jia, Guohua
    Deng, Degang
    Hua, Youjie
    Zhao, Shilong
    Huang, Lihui
    Wang, Huanping
    Ma, Hongping
    Xu, Shiqing
    JOURNAL OF LUMINESCENCE, 2012, 132 (01) : 153 - 160
  • [49] Co-cation Conduction in Solid Solutions (K1 – xRbx)4P2O7–M2P2O7(M = Ca, Sr, Cd, Ba): Dependence on the Nature and Concentration of Cations M2+
    N. B. Smirnov
    E. I. Burmakin
    B. D. Antonov
    G. Sh. Shekhtman
    Russian Journal of Electrochemistry, 2001, 37 : 322 - 325
  • [50] Crystal structure of EU2+-doped M3MgSi2O2 (M: Ba, Sr, Ca) compounds and their emission properties
    Yonesaki, Yoshinori
    Takei, Takahiro
    Kumada, Nobuhiro
    Kinomura, Nobukazu
    JOURNAL OF SOLID STATE CHEMISTRY, 2009, 182 (03) : 547 - 554