Entangled Valence Electron-Hole Dynamics Revealed by Stimulated Attosecond X-ray Raman Scattering

被引：25
|
作者：
Healion, Daniel [1 ]
Zhang, Yu [1 ]
Biggs, Jason D. [1 ]
Govind, Niranjan [2 ]
Mukamel, Shaul [1 ]
机构：
[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA
[2] Pacific NW Natl Lab, William R Wiley Environm Mol Sci Lab, Richland, WA 99352 USA
来源：
JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2012年 / 3卷 / 17期
基金：
美国国家科学基金会; 美国国家卫生研究院;
关键词：
DENSITY-FUNCTIONAL THEORY; SPECTROSCOPY;
D O I：
10.1021/jz300981w
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We show that broadband X-ray pulses can create wavepackets of valence electrons and holes localized in the vicinity of a selected atom (nitrogen, oxygen, or sulfur in cysteine) by stimulated resonant Raman scattering. The subsequent dynamics reveals highly correlated motions of entangled electron and hole quasiparticles. This information goes beyond the time-dependent total charge density derived from X-ray diffraction.
引用
收藏
页码：2326 / 2331
页数：6
相关论文
共 50 条
  • [31] X-RAY RAMAN SCATTERING
    SUZUKI, T
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1966, 21 (10) : 2087 - &
  • [32] Effect of Rabi dynamics in resonant x-ray scattering of intense attosecond pulses
    Venkatesh, Akilesh
    Ho, Phay J.
    PHYSICAL REVIEW A, 2025, 111 (02)
  • [33] Attosecond X-ray free electron laser
    Kumar, S.
    Kang, H. S.
    Kim, D. E.
    XVIIITH INTERNATIONAL CONFERENCE ON ULTRAFAST PHENOMENA, 2013, 41
  • [34] Monitoring conical intersections in the ring opening of furan by attosecond stimulated X-ray Raman spectroscopy
    Hua, Weijie
    Oesterling, Sven
    Biggs, Jason D.
    Zhang, Yu
    Ando, Hideo
    de Vivie-Riedle, Regina
    Fingerhut, Benjamin P.
    Mukamel, Shaul
    STRUCTURAL DYNAMICS-US, 2016, 3 (02):
  • [35] Membrane Protein Dynamics Revealed by X-Ray Scattering with a Femtosecond Free-Electron Laser
    Grant, Thomas D.
    Perera, Suchithranga M.
    Salas-Estrada, Leslie A.
    Struts, Andrey V.
    Chawla, Udeep
    Xu, Xiaolin
    Fried, Steven D.
    Weerasinghe, Nipuna
    Mendez, D.
    Alvarez, R.
    Karpos, K.
    Lisova, S.
    Zaare, S.
    Nazari, R.
    Zatsepsin, N. A.
    Singharoy, Abhishek
    Boutet, S.
    Carbajo, S.
    Hunter, M. S.
    Liang, M.
    Seaberg, M. D.
    Fromme, Raimund
    Fromme, Petra
    Grossfield, Alan
    Kirian, Richard A.
    Brown, Michael F.
    BIOPHYSICAL JOURNAL, 2020, 118 (03) : 365A - 365A
  • [36] On the sensitivity of electron and X-ray scattering factors to valence charge distributions
    Zheng, JC
    Zhu, YM
    Wu, LJ
    Davenport, JW
    JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2005, 38 : 648 - 656
  • [37] INFLUENCE OF VALENCE ELECTRON SCATTERING ON RESULTS OF X-RAY STRUCTURE ANALYSES
    OCONNELL, AM
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1969, B 25 : 1273 - +
  • [38] EXACT SOLUTION OF THE X-RAY EDGE PROBLEM WITH NO ELECTRON-HOLE PAIR EXCITATIONS
    PENN, DR
    GIRVIN, S
    BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1981, 26 (03): : 470 - 470
  • [39] Kinetics of electron-hole recombination in X-ray irradiated cubic stabilized zirconia
    Azzoni, CB
    Bolis, L
    Paleari, A
    NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1996, 116 (1-4): : 191 - 194
  • [40] Strong-field control and spectroscopy of attosecond electron-hole dynamics in molecules
    Smirnova, Olga
    Patchkovskii, Serguei
    Mairesse, Yann
    Dudovich, Nirit
    Ivanov, Misha Yu
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2009, 106 (39) : 16556 - 16561
12345