Thermal decomposition of silver acetate in silver paste for solar cell metallization: An effective route to reduce contact resistance

被引：11

作者：

Kim, Suk Jun ^{[1
]}

Kim, Se Yun ^{[1
]}

Park, Jin Man ^{[1
]}

Park, Keum Hwan ^{[1
]}

Lee, Jun Ho ^{[1
]}

Lee, Sang Mock ^{[1
]}

Han, In Taek ^{[1
]}

Kim, Do Hyang ^{[2
]}

Lim, Ka Ram ^{[2
]}

Kim, Won Tae ^{[3
]}

Park, Ju Cheol ^{[4
]}

Jee, Sang Soo ^{[1
]}

Lee, Eun-Sung ^{[1
]}

机构：

[1] SAIT, Elect Mat Lab, Yongin 446712, Gyeonggi Do, South Korea

[2] Yonsei Univ, Ctr Noncrystalline Mat, Dept Mat Sci & Engn, Seoul 120749, South Korea

[3] Cheongju Univ, Dept Opt Engn, Cheongju 360764, South Korea

[4] Seoul Natl Univ, Res Inst Adv Mat, Seoul 151742, South Korea

来源：

APPLIED PHYSICS LETTERS | 2013年 / 103卷 / 06期

关键词：

ALUMINUM;

D O I：

10.1063/1.4818124

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

A screen printed silver/metallic glass (MG) paste formulated with Ag acetate resulted in a specific contact resistance in the range of 0.6-0.7 m Omega.cm(2) on both the n- and p-type Si emitters of interdigitated back-contact solar cells. Silver nanocrystallites resulting from thermally decomposed Ag acetate prevented the Al MG frits from directly interacting with the Si emitter, thus reducing the amount of Al diffused into the Si emitters, and subsequently, the contact resistance. A photovoltaic conversion efficiency of 20.3% was achieved using this technique. (C) 2013 AIP Publishing LLC.

引用

页数：4

共 50 条

[21] -Irradiation effects on the kinetics and mechanism of the thermal decomposition of silver acetate
Mahfouz, R. M.
Bumajdad, A.
Al-Sagheer, F. A.
RADIATION EFFECTS AND DEFECTS IN SOLIDS, 2009, 164 (03): : 170 - 177
[22] Thermal Decomposition of Silver Acetate: Physico-Geometrical Kinetic Features and Formation of Silver Nanoparticles
Nakano, Masayoshi
Fujiwara, Takayuki
Koga, Nobuyoshi
JOURNAL OF PHYSICAL CHEMISTRY C, 2016, 120 (16): : 8841 - 8854
[23] Effect of glass frit composition on reliability of silver paste metallization in crystalline silicon solar cells
Li, Huixin
Sun, Xinjie
Xing, Juanjuan
Yang, Yunxia
Yuan, Xiao
Tong, Hua
MATERIALS RESEARCH EXPRESS, 2024, 11 (05)
[24] Research progress and prospect of the conductive silver paste for solar cell
Yan F.
Gan G.
Teng Y.
Kang K.
Yan J.
Yi J.
Cailiao Daobao/Materials Review, 2016, 30 (02): : 139 - 143
[25] Application of CTLM method combining interfacial structure characterization to investigate contact formation of silver paste metallization on crystalline silicon solar cells
Xiong, Shenghu
Yuan, Xiao
Tong, Hua
Yang, Yunxia
Liu, Cui
Ye, Xiaojun
Li, Yongsheng
Wang, Xianhao
Luo, Lan
SOLID-STATE ELECTRONICS, 2018, 142 : 1 - 7
[26] Silver ink experiments for silicon solar cell metallization by flexographic process
Thibert, S.
Chaussy, D.
Beneventi, D.
Reverdy-Bruas, N.
Jourdan, J.
Bechevet, B.
Mialon, S.
2012 38TH IEEE PHOTOVOLTAIC SPECIALISTS CONFERENCE (PVSC), 2012, : 2266 - 2270
[27] Thermal-decomposition and crystallization behaviour of coupling agents for silver paste application
Shih, CJ
Shih, SJ
Lin, HC
Yeh, HH
Hung, YC
NANOTECHNOLOGY, 2003, 14 (09) : 1014 - 1018
[28] Ohimc Contact Formation Mechanism of Silver–Aluminum Paste Metallization on the p+ Emitter of n-Type Crystalline Silicon Solar Cells
Xinjie Sun
Juanjuan Xing
Yunxia Yang
Xiao Yuan
Hongbo Li
Hua Tong
Journal of Electronic Materials, 2022, 51 : 5717 - 5722
[29] Synthesis of Silver-coated Copper Particles with Thermal Oxidation Stability for a Solar Cell Conductive Paste
Shin, Jongmin
Kim, Hyunju
Song, Kwang Ho
Choe, Jaehoon
CHEMISTRY LETTERS, 2015, 44 (09) : 1223 - 1225
[30] Preparation of silver powder used for solar cell paste by reduction process
Moudir, N.
Boukennous, Y.
Moulai-Mostefa, N.
Bozetine, I.
Maoudj, M.
Kamel, N.
Kamel, Z.
Moudir, D.
TERRAGREEN 13 INTERNATIONAL CONFERENCE 2013 - ADVANCEMENTS IN RENEWABLE ENERGY AND CLEAN ENVIRONMENT, 2013, 36 : 1184 - 1191

← 1 2 3 4 5 →