Monopotassium monosodium hexahydrogen α-hexamolybdoplatinate(IV) hexahydrate

被引：12

作者：

Lee, Uk ^{[1
]}

Joo, Hea-Chung ^{[1
]}

机构：

[1] Pukyong Natl Univ, Dept Chem, Nam Ku, Pusan 608737, South Korea

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷

关键词：

D O I：

10.1107/S1600536806043157

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, KNa[H-6 alpha-PtMo6O24]center dot 6H(2)O, containing the hexamolybdoplatinate(IV) polyanion with the highest level of protonation, was isolated at pH = 0.48. The anion has the Pt atom at an inversion center and has local symmetry close to 3m; there are two independent half-anions in the asymmetric unit. Four O atoms of the central PtO6 octahedron and two O atoms of the edge-shared MoO6 octahedron are protonated. One Na atom occupies an inversion center.

引用

页码：I231 / I233

页数：3

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