Monopotassium monosodium hexahydrogen α-hexamolybdoplatinate(IV) hexahydrate

被引：12
|
作者：
Lee, Uk [1 ]
Joo, Hea-Chung [1 ]
机构：
[1] Pukyong Natl Univ, Dept Chem, Nam Ku, Pusan 608737, South Korea
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷
关键词：
D O I：
10.1107/S1600536806043157
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, KNa[H-6 alpha-PtMo6O24]center dot 6H(2)O, containing the hexamolybdoplatinate(IV) polyanion with the highest level of protonation, was isolated at pH = 0.48. The anion has the Pt atom at an inversion center and has local symmetry close to 3m; there are two independent half-anions in the asymmetric unit. Four O atoms of the central PtO6 octahedron and two O atoms of the edge-shared MoO6 octahedron are protonated. One Na atom occupies an inversion center.
引用
收藏
页码：I231 / I233
页数：3
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