Synthesis and characterization of diruthenium complexes in low oxidation states. Formation of mono- and bis-CO adducts

被引：15
|
作者：
Kadish, KN
Han, BC
Shao, JG
Ou, ZP
Bear, JL
机构：
[1] Univ Houston, Dept Chem, Houston, TX 77204 USA
[2] Univ Wisconsin, Whitewater, WI 53190 USA
来源：
INORGANIC CHEMISTRY | 2001年 / 40卷 / 26期
关键词：
D O I：
10.1021/ic010907d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A monocarbonyl diruthenium(Il,fl) complex of the type (dpf)(4)Ru-2(CO), where dpf is N,N'-diphenylformamidinate, was characterized as to its electrochemical and spectroscopic properties (UV-vis, FTIR, and ESR) under a N-2 or CO atmosphere. The synthesis and X-ray structural characterization of (dpf)(4)Ru-2(CO) are also presented.
引用
收藏
页码：6848 / +
页数：5
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