Bulk liquid membrane for the recovery of chromium(VI) from a hydrochloric acid medium using dicyclohexano-18-crown-6 as extractant-carrier

被引：40

作者：

Zouhri, A

Ernst, B

Burgard, M ^{[1
]}

机构：

[1] Ecole Europeenne Chim Polymeres & Materiaux Stras, UMR 7512 CNRS, Lab Chim Minerale & Analyt, F-67087 Strasbourg, France

[2] Univ Ibnou Zohr, Fac Sci, Agadir, Morocco

来源：

SEPARATION SCIENCE AND TECHNOLOGY | 1999年 / 34卷 / 09期

关键词：

liquid membrane; chromium; extraction; transport; dicyclohexano-18-crown-6;

D O I：

10.1081/SS-100100745

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The solvent extraction and transfer of chromic acid from hydrochloric acid medium through a bulk liquid membrane containing dicyclohexano-18-crown-6(L) were studied. Extraction experiments pointed out that chromium(VI) was coextracted with the chloride ion which formed the complex ion pair L(H3O+)CrO3Cl- in the organic phase. The Donnan equilibrium isotherm based on the extraction, stripping, and CrO3Cl- hydrolysis equilibria allowed prediction of the performance of the semipermeable membrane to concentrate chlorochromic acid in the receiving phase. Transport experiments confirmed the ability of the liquid membrane to recover chlorochromic acid in pure water. The transport kinetics was modeled by using the two-film theory applied to the liquid membrane.

引用

页码：1891 / 1905

页数：15

共 50 条

[41] RAPID SEPARATION OF TL+ AND PB-2+ FROM VARIOUS BINARY CATION MIXTURES USING DICYCLOHEXANO-18-CROWN-6 INCORPORATED INTO EMULSION MEMBRANES
IZATT, RM
BIEHL, MP
LAMB, JD
CHRISTENSEN, JJ
SEPARATION SCIENCE AND TECHNOLOGY, 1982, 17 (11) : 1351 - 1360
[42] Liquid-liquid Extraction and Recovery of Pd(II) from Nitric Acid Medium Using Green Diesel as Extractant
Masry, Botros Abdelnaser
Zeid, Mohammad Mohammad
Kassem, Amany Taghian
Noweir, Hala Gamal
Saad, Ebtissam Ahmad
Daoud, Jacqueline Abdel Messih
JOURNAL OF PHYSICAL SCIENCE, 2018, 29 (02) : 25 - 48
[43] Selective bulk liquid membrane transport of metal ions using dibenzopyridinio-18-crown-6 as ionophore
Rounaghi, G. H.
Kazemi, M. S.
ASIAN JOURNAL OF CHEMISTRY, 2008, 20 (01) : 366 - 374
[44] Study of competitive transport of metal cations through bulk liquid membrane using 4′-nitrobenzo-18-crown-6 and diaza-18-crown-6
Rounaghi, Gholam Hossein
Hosseiny, Malihe Sadat
Chamsaz, Mahmud
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2011, 69 (1-2) : 221 - 229
[45] Study of competitive transport of metal cations through bulk liquid membrane using 4′-nitrobenzo-18-crown-6 and diaza-18-crown-6
Gholam Hossein Rounaghi
Malihe Sadat Hosseiny
Mahmud Chamsaz
Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2011, 69 : 221 - 229
[46] Highly selective transport of lead cation through bulk liquid membrane by macrocyclic ligand of decyl-18-crown-6 as carrier
Kazemi, Malihe S.
Rounaghi, Golamhossein
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2010, 55 (12) : 1987 - 1991
[47] Highly selective transport of lead cation through bulk liquid membrane by macrocyclic ligand of decyl-18-crown-6 as carrier
Malihe S. Kazemi
Golamhossein Rounaghi
Russian Journal of Inorganic Chemistry, 2010, 55 : 1987 - 1991
[48] Removal of Chromium(VI) from Industrial Effluents Through Supported Liquid Membrane Using Trioctylphosphine Oxide as a Carrier
Nawaz, Robila
Ali, Khurshid
Ali, Nauman
Khaliq, Alia
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2016, 27 (01) : 209 - 220
[49] Kinetic study of chromium(VI) facilitated transport through a bulk liquid membrane using tri-n-butyl phosphate as carrier
Zhang, Weidong
Liu, Junteng
Ren, Zhongqi
Wang, Shuguang
Du, Changshun
Ma, Jingnan
CHEMICAL ENGINEERING JOURNAL, 2009, 150 (01) : 83 - 89
[50] Kinetic study of chromium(VI) facilitated transport through a bulk liquid membrane using tri-n-butyl phosphate as carrier
Zhang, Weidong
Liu, Junteng
Ren, Zhongqi
Wang, Shuguang
Du, Changshun
Ma, Jingnan
Chemical Engineering Journal, 2009, 150 (01): : 83 - 89

← 1 2 3 4 5 →