Synthesis, crystal structure and magnetic properties of a new 1-D oxamidate-bridged Cu(II)-Mn(II) polymer

被引：7

作者：

Lou, Weijiang ^{[1
]}

Zang, Shuangquan ^{[2
,3
]}

Zhang, Wu ^{[1
]}

Wang, Qinglun ^{[4
]}

Tao, Ruojie ^{[1
]}

机构：

[1] Henan Univ, Coll Chem & Chem Engn, Inst Mol & Crystal Engn, Kaifeng 475001, Peoples R China

[2] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China

[3] Chinese Univ Hong Kong, Ctr Novel Funct Mol, Shatin, Hong Kong, Peoples R China

[4] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2008年 / 61卷 / 22期

关键词：

Oxamidate-bridged; Coordination polymer; Crystal structure; Magnetic properties;

D O I：

10.1080/00958970802105052

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new coordination polymer, {[Cu(aeop)Mn(H(2)O)(3)](2)}n (H(4)aeop = N'-(2-aminoterephthalic acid)-N''-(1,3-propanediamine)oxamidate), has been synthesized and characterized structurally and magnetically. This complex features a 1-D ladder-like chain structure constructed from neutral tetranuclear units through the syn-anti carboxylate bridges. This crystal forms in the triclinic system, space group P (1) over bar, with a = 9.653(1) angstrom, b = 9.686(1) angstrom, c = 10.903(1) angstrom, alpha = 80.984(1)degrees, beta = 69.776(1)degrees, gamma = 80.729(1)degrees and z = 2. The relationship between its magnetic properties and structure has also been investigated.

引用

页码：3642 / 3650

页数：9

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