Suzuki-Miyaura Coupling of Aryl Iodides, Bromides, and Chlorides Catalyzed by Bis(thiazole) Pincer Palladium Complexes

被引：39

作者：

Luo, Qun-Li ^{[1
]}

Tan, Jian-Ping ^{[1
]}

Li, Zhi-Fu ^{[1
]}

Nan, Wen-Hui ^{[1
]}

Xiao, Dong-Rong ^{[1
]}

机构：

[1] Southwest Univ, Coll Chem & Chem Engn, Chongqing 400715, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 77卷 / 18期

关键词：

PALLADACYCLES; PRECURSOR; PYRIDINE; LIGANDS;

D O I：

10.1021/jo3011733

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bis(thiazole) pincer palladium complexes showed efficient catalytic activity for the Suzuki-Miyaura coupling of aryl halides, allowing the synthesis of biaryls with very high turnover numbers and turnover frequencies. The complexes were successfully applied in the scalable and green synthesis of the key intermediates of bioactive LUF5771 and its analogues.

引用

页码：8332 / 8337

页数：6

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