Hydrophobic Metal Halide Perovskites for Visible-Light Photoredox C-C Bond Cleavage and Dehydrogenation Catalysis

被引：91
|
作者：
Hong, Zonghan [1 ]
Chong, Wee Kiang [2 ]
Ng, Andrew Yun Ru [1 ]
Li, Mingjie [2 ]
Ganguly, Rakesh [1 ]
Sum, Tze Chien [2 ]
Soo, Han Sen [1 ,3 ]
机构：
[1] Nanyang Technol Univ, Div Chem & Biol Chem, Sch Phys & Math Sci, 21 Nanyang Link, Singapore 637371, Singapore
[2] Nanyang Technol Univ, Div Phys & Appl Phys, Sch Phys & Math Sci, 21 Nanyang Link, Singapore 637371, Singapore
[3] Nanyang Technol Univ, Solar Fuels Lab, 50 Nanyang Ave, Singapore 639798, Singapore
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2019年 / 58卷 / 11期
关键词：
decarboxylation; hydrophobic perovskites; photocatalysis; photooxidation; two-dimensional materials; HYDROGEN EVOLUTION; EMISSION; ELECTRON; CO2; ABSORPTION; COMPLEXES; REDUCTION; DOTS;
D O I：
10.1002/anie.201812225
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two-dimensional lead and tin halide perovskites were prepared by intercalating the long alkyl group 1-hexadecylammonium (HDA) between the inorganic layers. We observed visible-light absorption, narrow-band photoluminescence, and nanosecond photoexcited lifetimes in these perovskites. Owing to their hydrophobicity and stability even in humid air, we applied these perovskites in the decarboxylation and dehydrogenation of indoline-2-carboxylic acids. (HDA)(2)PbI4 or (HDA)(2)SnI4 were investigated as photoredox catalysts for these reactions, and quantitative conversion and high yields were observed with the former.
引用
收藏
页码：3456 / 3460
页数：5
相关论文
共 50 条
  • [21] Applications of Photoredox Catalysis for the Radical-Induced Cleavage of C-C Bonds
    Vanderghinste, Jaro
    Das, Shoubhik
    SYNTHESIS-STUTTGART, 2022, 54 (15): : 3383 - 3398
  • [22] Visible-light photoredox-catalyzed dual C-C bond cleavage: synthesis of 2-cyanoalkylsulfonylated 3,4-dihydronaphthalenes through the insertion of sulfur dioxide
    Liu, Yu
    Wang, Qiao-Lin
    Chen, Zan
    Li, Hua
    Xiong, Bi-Quan
    Zhang, Pan-Liang
    Tang, Ke-Wen
    CHEMICAL COMMUNICATIONS, 2020, 56 (20) : 3011 - 3014
  • [23] Visible-light photoredox-catalyzed C–O bond cleavage of diaryl ethers by acridinium photocatalysts at room temperature
    Fang-Fang Tan
    Xiao-Ya He
    Wan-Fa Tian
    Yang Li
    Nature Communications, 11
  • [24] Metal- and additive-free C-H oxygenation of alkylarenes by visible-light photoredox catalysis
    Uygur, Mustafa
    Kuhlmann, Jan H.
    Perez-Aguilar, Maria Carmen
    Piekarski, Dariusz G.
    Mancheno, Olga Garcia
    GREEN CHEMISTRY, 2021, 23 (09) : 3392 - 3399
  • [25] Metal-Free, Visible-Light-Induced Selective C-C Bond Cleavage of Cycloalkanones with Molecular Oxygen
    Guo, Li-Na
    Xin, Hong
    Duan, Xin-Hua
    Liu, Le
    CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (51) : 11690 - 11694
  • [26] Singlet oxygen mediated dual C-C and C-N bond cleavage in visible light
    Ritu
    Sharma, Charu
    Kumar, Sharvan
    Jain, Nidhi
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2020, 18 (15) : 2921 - 2928
  • [27] Metal-Free Catalysis in C-C Single-Bond Cleavage: Achievements and Prospects
    Deb, Mohit L.
    Saikia, B. Shriya
    Rahman, Iftakur
    Baruah, Pranjal Kumar
    TOPICS IN CURRENT CHEMISTRY, 2022, 380 (05)
  • [28] Selective C-O Bond Cleavage of Lignin Systems and Polymers Enabled by Sequential Palladium-Catalyzed Aerobic Oxidation and Visible-Light Photoredox Catalysis
    Magallanes, Gabriel
    Karkas, Markus D.
    Bosque, Irene
    Lee, Sudarat
    Maldonado, Stephen
    Stephenson, Corey R. J.
    ACS CATALYSIS, 2019, 9 (03): : 2252 - 2260
  • [29] Visible-light-induced C-C bond cleavage of lignin model compounds with cyanobenziodoxolone
    Zheng, Ming
    Huang, Yan
    Zhan, Le-Wu
    Hou, Jing
    Li, Bin-Dong
    TETRAHEDRON LETTERS, 2020, 61 (42)
  • [30] Visible-light photoredox-catalyzed C-O bond cleavage of diaryl ethers by acridinium photocatalysts at room temperature
    Tan, Fang-Fang
    He, Xiao-Ya
    Tian, Wan-Fa
    Li, Yang
    NATURE COMMUNICATIONS, 2020, 11 (01)
12345