Hydrothermal synthesis and characterization of LaIII and CuII coordination polymers with 5-nitroisophthalic acid (H2Nip), [La2(μ-NiP)(μ-SO4)2(H2O)5]n and {[Cu3(μ-OH)2(μ-NiP)2(μ-H2O)2]•2H2O}n

被引:6
|
作者
Xiao, Hong-Ping [1 ]
Li, Xin-Hua [1 ]
Shi, Qian [1 ]
Zhang, Wei-Bing [1 ]
Wang, Jia-Guo [1 ]
Morsali, Ali [2 ]
机构
[1] Wenzhou Univ, Sch Chem & Mat Sci Engn, Wenzhou, Peoples R China
[2] Tarbiat Modares Univ, Sch Sci, Dept Chem, Tehran 141554838, Iran
关键词
Lanthanide(III); Copper(II); 5-nitroisophthalate; coordination polymer;
D O I
10.1080/00958970801986809
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
3D La-III and 2D Cu-II coordination polymers with 5-nitroisophthalate anions, [La-2(mu-Nip) (mu-SO4)(2)(H2O)(5)](n) (1) and {[Cu-3(mu-OH)(2)(mu Nip)(2)(mu-H2O)(2)]center dot 2H(2)O}(n) (2) have been synthesized, characterized and studied by X-ray crystallography. The La atoms have eight-coordinate geometries in distorted square antiprism environments and the Cu atoms have five- and six-coordinate geometries with distorted square pyramidal anti octahedral environments. Self-assembly of these compounds in the solid state occurs through coordination and hydrogen bonding.
引用
收藏
页码:2905 / 2915
页数:11
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