Synthesis, Crystal Structure and Fluorescent Properties of Dinuclear Zinc Complex

被引：0

作者：

Bi, Chenglu ^{[1
]}

Li, Weihua ^{[1
]}

Lu, Hui ^{[1
]}

Zhang, Hui ^{[1
]}

Sun, Jianhua ^{[1
]}

机构：

[1] Jiangsu Univ Technol, Sch Chem & Environm Engn, Jiangsu Key Lab Precious Met Chem, Changzhou 213001, Peoples R China

来源：

ASIAN JOURNAL OF CHEMISTRY | 2014年 / 26卷 / 03期

关键词：

Zinc complex; Crystal structure; Dinuclear; Fluorescence; QUINOLINE; CHEMOSENSOR; FRAMEWORKS; IONS;

D O I：

10.14233/ajchem.2014.15525

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A dinuclear zinc complex [Zn-2(qnal)(2)(CH3COO)(2)] (Hqnal: N-(8'-quinolyl)-2-hydroxy-1-naphthaldimine) was synthesized and characterized by X-ray crystallography. The complex crystallizes in monoclinic system, space group C2/c with a = 40.00(3), b = 7.690(5), c = 27.492(16) angstrom, beta = 120.446(11)degrees, V = 17290(8) angstrom(3), Z = 8. D-c = 1.537 g/cm(3), M-r = 843.48, F(000) = 3456, mu(MoKa) = 1.374 mm(-1), S = 1.033, R = 0.0403 and wR = 0.1049 for 4454 observed reflections (I > 2 sigma(I)). It exhibits a 3D supramolecular architecture constructing by pi-pi stacking interactions between quinolyl and naphthyl rings and shows luminescent property in the yellow region.

引用

页码：761 / 763

页数：3

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