Synthesis, properties and molecular structures of cobalt(II), copper(II) and zinc(II) complexes with 1,2-bis [3-(pyrazol-1-yl)-2-oxapropyl]benzene

被引：0
|
作者：
Sheu, SC [1 ]
Tien, MJ [1 ]
Cheng, MC [1 ]
Ho, TI [1 ]
Peng, SM [1 ]
Lin, YC [1 ]
机构：
[1] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI 10764,TAIWAN
来源：
POLYHEDRON | 1996年 / 15卷 / 5-6期
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D O I：
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中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The new ligand 1,2-bis[3-(pyrazol-1-yl)-2-oxapropyl]benzene (L), reacted with cobalt(II) chloride, copper(II) chloride and zinc(II) chloride to form [CoLCl(2)], [CuLCl(2)] and [ZnLCl(2)], respectively. The structures of these metal complexes have been determined by X-ray crystallography. The Co and Zn structures are isomorphous with distorted tetrahedral metal geometries. The coordination sphere of the copper(II) ion in its complex is intermediate between distorted tetrahedral and distorted square-pyramidal geometry, if a weak Cu ... O interaction is taken into account.
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页码：961 / 965
页数：5
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