Biologically inspired oxidation catalysis using metallopeptides

被引：16

作者：

Vicens, Laia

Costas, Miquel ^{[1
]}

机构：

[1] Univ Girona, IQCC, Campus Montilivi, E-17071 Girona, Catalonia, Spain

来源：

DALTON TRANSACTIONS | 2018年 / 47卷 / 06期

关键词：

HIGHLY ENANTIOSELECTIVE EPOXIDATION; ASYMMETRIC CIS-DIHYDROXYLATION; ELECTRON-DEFICIENT ALKENES; NONHEME IRON-CATALYSTS; SOLID-PHASE SYNTHESIS; AMINO-ACIDS; HYDROGEN-PEROXIDE; SYNTHETIC ENZYMES; C-H; STEREOSELECTIVE EPOXIDATION;

D O I：

10.1039/c7dt03657d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The stereoselective oxidation of hydrocarbons is one of the most challenging reactions for synthetic chemists. However, this transformation is one of the most common reactions in nature. Metalloenzymes that catalyze this transformation are taken as inspiration for the development of new catalysts. There are several examples in the literature where either peptides or metal catalysts are used in the stereoselective oxidation reaction, but the synergistic combination of both systems is still a non-explored field. The use of metallopeptides in biologically inspired oxidation reactions is discussed in this perspective.

引用

页码：1755 / 1763

页数：9

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