Preparation and Interfacial Properties of Phosphonic Acid-Terminated Self-Assembled Monolayers on Gold Surface

被引：32

作者：

Chen, Yu ^{[1
]}

Yang, Xiao-Jing ^{[1
]}

Jin, Bo ^{[2
]}

Guo, Li-Rong ^{[1
]}

Zheng, Li-Min ^{[1
]}

Xia, Xing-Hua ^{[2
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China

[2] Nanjing Univ, Key Lab Analyt Chem Life Sci, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2009年 / 113卷 / 11期

关键词：

QUARTZ-CRYSTAL MICROBALANCE; AU(111) SINGLE-CRYSTAL; CYCLIC VOLTAMMETRY; MOLECULAR FILMS; CARBOXYLIC-ACID; ELECTROCHEMICAL CHARACTERIZATION; ELECTROLESS DEPOSITION; TITRATION; ADSORPTION; STABILITY;

D O I：

10.1021/jp808195j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The preparation and interfacial properties of self-assembled monolayers (SAMs) of 3-mercaptopropylphosphonic acid [HS-(CH2)(3)-PO3H2, MPPA] adsorbed on Au surfaces have been systematically investigated with the electrochemical method, X-ray photoelectron spectroscopy (XPS), and surface-enhanced internal reflection infrared spectroscopy measurements. An improved rinse method (base-acid rinse protocol) is presented to prepare the MPPA monolayers free of unbound MPPA thiols. Experimental results show that the effect of the degree of dissociation of -PO3H2 groups on the compactness of MPPA-SAMs is nonlinear possibly because of hydrogen bond interaction and the dibasic nature and hydrophilicity of the -PO3H2 groups. The effects of pH and the electric field on the surface charge of MPPA-SAMs are investigated.

引用

页码：4515 / 4521

页数：7

共 50 条

[11] Electric field driven protonation/deprotonation of self-assembled monolayers of acid-terminated thiols
Burgess, I
Seivewright, B
Lennox, RB
LANGMUIR, 2006, 22 (09) : 4420 - 4428
[12] Reactivity of acid fluoride-terminated self-assembled monolayers on gold
Chi, Young Shik
Lee, Kyung-Bok
Kim, Yongseong
Choi, Insung S.
LANGMUIR, 2007, 23 (03) : 1209 - 1214
[13] Influence of gold topography on carboxylic acid terminated self-assembled monolayers
Leopold, MC
Black, JA
Bowden, EF
LANGMUIR, 2002, 18 (04) : 978 - 980
[14] INTERFACIAL BUFFER EFFECT OF SELF-ASSEMBLED MONOLAYERS OF A CARBOXYLIC-ACID TERMINATED ALKANETHIOL ON A GOLD ELECTRODE
KUNITAKE, M
DEGUCHI, Y
KAWATANA, K
MANABE, O
NAKASHIMA, N
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (05) : 563 - 564
[15] Improvements in the characterization of the crystalline structure of acid-terminated alkanethiol self-assembled monolayers on Au(111)
Mendoza, Sandra M.
Arfaoui, Imad
Zanarini, Simone
Paolucci, Francesco
Rudolf, Petra
LANGMUIR, 2007, 23 (02) : 582 - 588
[16] Hydrogen bond dynamics at the interface between water and carboxylic acid-terminated self-assembled monolayers
Winter, Nicolas D.
Vieceli, John S.
Benjamin, Ilan
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233
[17] Electron Transfer Binding Site of Cytochrome c to Carboxylic Acid-Terminated Alkanethiol Self-assembled Monolayers Immobilized on Gold Electrode
K. Niki
K. R. Pressler
J. R. Sprinkle
H. Li
E. Margoliash
Russian Journal of Electrochemistry, 2002, 38 : 63 - 67
[18] Electron transfer binding site of cytochrome c to carboxylic acid-terminated alkanethiol self-assembled monolayers immobilized on gold electrode
Niki, K
Pressler, KR
Sprinkle, JR
Li, H
Margoliash, E
RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2002, 38 (01) : 63 - 67
[19] Study on surface acid-base property of carboxylic acid-terminated self-assembled monolayers by cyclic voltammetry and electrochemical impedance spectroscopy
罗立强
程志亮
杨秀荣
汪尔康
ChineseJournalofChemistry, 2000, (06) : 863 - 867
[20] Characterization of carboxylic acid-terminated self-assembled monolayers by electrochemical impedance spectroscopy and scanning electrochemical microscopy
Sanders, Wesley
Vargas, Ricardo
Anderson, Mark R.
LANGMUIR, 2008, 24 (12) : 6133 - 6139

← 1 2 3 4 5 →