Microwave assisted, highly efficient solid state N- and S-alkylation

被引：12
|
作者：
Jaisinghani, HG [1 ]
Khadilkar, BM [1 ]
机构：
[1] Univ Bombay, Dept Chem Technol, Bombay 400019, Maharashtra, India
来源：
SYNTHETIC COMMUNICATIONS | 1999年 / 29卷 / 21期
关键词：
D O I：
10.1080/00397919908086007
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Secondary amines and thiophenols were alkylated with alkyl and benzyl halides rapidly on alumina supported potassium carbonate under solvent-free conditions using microwaves. Equimolar amounts of the secondary amine/thiophenol and alkyl halide were used. The procedure neither required any strong base nor a PTC. Aniline was also monobenzylated with benzylchloride. Separation of the products from the reactants was very simple by using a nonpolar solvent for desorption.
引用
收藏
页码：3693 / 3698
页数：6
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