"Eggs in egg cartons": co-crystallization to embed molecular cages into crystalline lattices

被引：15

作者：

Domoto, Yuya ^{[1
]}

Abe, Masahiro ^{[1
]}

Yamamoto, Kidai ^{[1
]}

Kikuchi, Takashi ^{[2
]}

Fujita, Makoto ^{[1
,3
]}

机构：

[1] Univ Tokyo, Dept Appl Chem, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1138656, Japan

[2] Rigaku Corp, 3-9-12 Matsubara Cho, Akishima, Tokyo 1968666, Japan

[3] Natl Inst Nat Sci, Inst Mol Sci, Div Adv Mol Sci, 5-1 Higashiyama Myodaiji Cho, Okazaki, Aichi 4448787, Japan

来源：

CHEMICAL SCIENCE | 2020年 / 11卷 / 38期

关键词：

METAL-ORGANIC FRAMEWORK; ALKYNE COMPLEXES; COPPER(I); SILVER(I);

D O I：

10.1039/d0sc03191g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Discrete (M3L2)(n)cages assembled from a tripodal ligand (L) and metal ions (M: Cu(i) or Ag(i)) are embedded in networked coordination hosts formed by partial dissociation of the same discrete cages during the crystallization process. The resulting "eggs-in-an-egg-carton" structures provide unique examples of the co-crystallization of discrete and infinite coordination frameworks.

引用

页码：10457 / 10460

页数：4

共 22 条

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