"Eggs in egg cartons": co-crystallization to embed molecular cages into crystalline lattices

被引：15
|
作者：
Domoto, Yuya [1 ]
Abe, Masahiro [1 ]
Yamamoto, Kidai [1 ]
Kikuchi, Takashi [2 ]
Fujita, Makoto [1 ,3 ]
机构：
[1] Univ Tokyo, Dept Appl Chem, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1138656, Japan
[2] Rigaku Corp, 3-9-12 Matsubara Cho, Akishima, Tokyo 1968666, Japan
[3] Natl Inst Nat Sci, Inst Mol Sci, Div Adv Mol Sci, 5-1 Higashiyama Myodaiji Cho, Okazaki, Aichi 4448787, Japan
来源：
CHEMICAL SCIENCE | 2020年 / 11卷 / 38期
关键词：
METAL-ORGANIC FRAMEWORK; ALKYNE COMPLEXES; COPPER(I); SILVER(I);
D O I：
10.1039/d0sc03191g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Discrete (M3L2)(n)cages assembled from a tripodal ligand (L) and metal ions (M: Cu(i) or Ag(i)) are embedded in networked coordination hosts formed by partial dissociation of the same discrete cages during the crystallization process. The resulting "eggs-in-an-egg-carton" structures provide unique examples of the co-crystallization of discrete and infinite coordination frameworks.
引用
收藏
页码：10457 / 10460
页数：4
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