X-ray Spectroscopic Analysis of the Growth of CBD-CdS Buffers on flexible Cu(In,Ga)Se2 Thin-Film Solar Cell Structures

被引：0
|
作者：
Wilks, R. G. [1 ]
Caballero, R. [1 ,2 ]
Song, X. [1 ]
Felix, R. [1 ]
Benkert, A. [1 ,3 ]
Gerlach, D. [1 ]
Weinhardt, L. [4 ,5 ]
Blum, M. [4 ,6 ]
Yang, W. [6 ]
Kaufmann, C. A. [1 ]
Heske, C. [4 ,5 ,7 ]
Schock, H. -W. [1 ]
Baer, M. [1 ,4 ,8 ]
机构：
[1] Helmholtz Zentrum Berlin Mat & Energie GmbH, Solar Energy Res, D-14109 Berlin, Germany
[2] Univ Autonoma Madrid, Dept Fis Aplicada, Madrid 28049, Spain
[3] Univ Wurzburg, Expt Phys 7, D-97074 Wurzburg, Germany
[4] Univ Nevada Las Vegas, Dept Chem, Las Vegas, NV 89154 USA
[5] Karlsruhe Inst Technol, Inst Synchrotron Radiat, D-76344 Eggenstein Leopoldshafen, Germany
[6] Lawrence Berkeley Natl Lab, Adv Light Source, Berkeley, CA 94720 USA
[7] Karlsruhe Inst Technol, Inst Chem Technol & Polymer Chem, D-76128 Karlsruhe, Germany
[8] Brandenburg Tech Univ Cottbus, Inst Chem & Phys, D-03046 Cottbus, Germany
来源：
2012 38TH IEEE PHOTOVOLTAIC SPECIALISTS CONFERENCE (PVSC) | 2012年
关键词：
chalcopyrite thin-film solar cells; CdS buffer; x-ray spectroscopy; interfaces; NA; HETEROJUNCTION; CUINSE2; SODIUM;
D O I：
暂无
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
The chemical bath deposition (CBD) of CdS layers on Cu(In,Ga)Se-2 ("CIGSe") absorbers on flexible polyimide substrates is examined using a combination of soft x-ray emission (XES) and photoelectron (XPS) spectroscopies. For this purpose, absorbers with with varying degrees of Cu-deficiency and NaF precursor thickness were studied. From the data, a detailed picture of the chemical surface composition (in particular the carbon and oxygen contamination) of the CBD-CdS layers can be drawn. The thickness and deposition rates were determined by monitoring the CdS-induced attenuation of the In 3d(5/2) XPS and In M-4,M-5 XES signals of the absorber, finding no significant impact of Na and/or Cu content of the CIGSe.
引用
收藏
页码：1682 / 1687
页数：6
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