One-pot synthesis of self-assembled heteroleptic palladium(II) complexes with tmeda: An application of ligand exchange reactions

被引：11

作者：

Bandi, Sreenivasulu ^{[1
]}

Debata, Niladri Bihari ^{[1
]}

Ramkumar, Venkatachalam ^{[1
]}

Chand, Dillip Kumar ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2014年 / 39卷

关键词：

Palladium(II); Self-assembly; Ligand exchange reaction; One-pot synthesis; PD-II IONS; COORDINATION-COMPLEXES; ENCAPSULATION; CAPSULE; DESIGN; SPHERE; ANION; CAGES; NM;

D O I：

10.1016/j.inoche.2013.10.047

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

One-pot synthesis of self-assembled heteroleptic complexes of general formula [Pd-x(tmeda)(x)(L)(y)](NO3)(2x) is achieved by combining required amount of tmeda, a chosen ligand L and Pd(NO3)(2) under suitable reaction conditions. The strategy is devised using our understanding of a special variety of ligand exchange reactions (LER) around palladium(II) centers as modeled in this work. The one-pot synthesis technique is thus considered as an application of the unique LER. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：75 / 78

页数：4

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