One-pot synthesis of self-assembled heteroleptic palladium(II) complexes with tmeda: An application of ligand exchange reactions

被引：11
|
作者：
Bandi, Sreenivasulu [1 ]
Debata, Niladri Bihari [1 ]
Ramkumar, Venkatachalam [1 ]
Chand, Dillip Kumar [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2014年 / 39卷
关键词：
Palladium(II); Self-assembly; Ligand exchange reaction; One-pot synthesis; PD-II IONS; COORDINATION-COMPLEXES; ENCAPSULATION; CAPSULE; DESIGN; SPHERE; ANION; CAGES; NM;
D O I：
10.1016/j.inoche.2013.10.047
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
One-pot synthesis of self-assembled heteroleptic complexes of general formula [Pd-x(tmeda)(x)(L)(y)](NO3)(2x) is achieved by combining required amount of tmeda, a chosen ligand L and Pd(NO3)(2) under suitable reaction conditions. The strategy is devised using our understanding of a special variety of ligand exchange reactions (LER) around palladium(II) centers as modeled in this work. The one-pot synthesis technique is thus considered as an application of the unique LER. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：75 / 78
页数：4
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