A highly selective, sensitive and stable fluorescent chemosensor based on Schiff base and poly(azomethine-urethane) for Fe3+ ions

被引：31

作者：

Kamaci, Musa ^{[1
,2
]}

Kaya, Ismet ^{[1
]}

机构：

[1] Canakkale Onsekiz Mart Univ, Dept Chem, Polymer Synth & Anal Lab, TR-17020 Canakkale, Turkey

[2] Piri Reis Univ, Dept Chem, Fac Sci & Letters, TR-34940 Istanbul, Turkey

来源：

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2017年 / 46卷

关键词：

Fluorescent probe; Fe (III) sensor; Polymer film; Chemosensor; Poly(azomethine-urethane); Contact angle's; LIVING CELLS; METAL-IONS; SENSOR; PROBE; SYSTEMS;

D O I：

10.1016/j.jiec.2016.10.035

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this paper, Schiff base (PAH) and its poly(azomethine-urethane) derivative (P-PAH) were synthesized and high-quality film sensor of these compounds could be easily fabricated on transparent polyester surface through dip-coating technique. Then, these films were used as fluorescence probes for the detection of metal ions in aqueous solutions. Photophysical properties of fluorescent films were investigated using fluorescence and UV-vis spectrometers. Fluorescence properties of probes were investigated in the presence of a series of different metal ions and the results showed that monomer and polymer films have a highly sensitive and selective response to Fe3+ ion in deionized water. Moreover, fluorescence measurements showed that the prepared fluorescent films have in the range 143-180 nm Stokes shift value. Also, contact angles of film probes were investigated and contact angles of PAH and P-PAH probes measured as 85 +/- 1 and 95 +/- 2 degrees, respectively. (C) 2016 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

引用

页码：234 / 243

页数：10

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