A practical method for synthesis of terminal 1,2-diols in high enantiomeric excess via oxazaborolidine-catalyzed asymmetric reduction

被引：32
|
作者：
Cho, BT [1 ]
Chun, YS [1 ]
机构：
[1] Hallym Univ, Dept Chem, Chunchon 200702, Kangwondo, South Korea
来源：
TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 10期
关键词：
D O I：
10.1016/S0957-4166(99)00184-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Asymmetric borane reduction of oc-hydroxy ketones protected with a tetrahydropyranyl (THP) group catalyzed by Corey's CBS reagent using N-phenylamine-borane complexes as the hydride source provided the corresponding terminal 1,2-diols with a very high enantiomeric excess. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1843 / 1846
页数：4
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