Metal-Organic Frameworks for Thin-Layer Chromatographic Applications

被引：15
|
作者：
Schenk, Claudia [1 ]
Kutzscher, Christel [1 ]
Drache, Franziska [1 ]
Helten, Stella [1 ]
Senkovska, Irena [1 ]
Kaskel, Stefan [1 ]
机构：
[1] Tech Univ Dresden, Inorgan Chem 1, Bergstr 66, D-01062 Dresden, Germany
来源：
ACS APPLIED MATERIALS & INTERFACES | 2017年 / 9卷 / 03期
关键词：
TLC; metal-organic frameworks; zirconium-based MOFs; DUT-67; planar chromatography; PLANAR CHROMATOGRAPHY; NATURAL BENZALDEHYDE; BETA-CYCLODEXTRIN; STATIONARY-PHASE; SEPARATION; ELECTROSPUN; STABILITY; CINNAMALDEHYDE; POLYMER;
D O I：
10.1021/acsami.6b13092
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Preparation of thin-layer chromatographic (TLC) plates based on metal-organic frameworks (MOFs) as porous stationary phases is described. DUT-67 (DUT = Dresden University of Technology), a zirconium based MOF, was used in combination with a fluorescent indicator as stationary phase for analyzing a small selection of a wide spectrum of relevant analytes. The successful separation of benzaldehyde from trans-cinnamaldehyde and 4-aminophenol from 2-aminotoluene is reported as a model system using optimized eluent mixtures containing acetic acid.
引用
收藏
页码：2006 / 2009
页数：4
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