2-Aminopyridinium bis(pyridine-2,6-dicarboxylato)ferrate(III)

被引：4
|
作者：
Mirzaei, Masoud [1 ]
Eshtiagh-Hosseini, Hossein [1 ]
Mague, Joel T. [2 ]
机构：
[1] Ferdowsi Univ Mashhad, Dept Chem, Mashhad 917791436, Iran
[2] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷
关键词：
CRYSTAL-STRUCTURE; PROTON-TRANSFER; DIHYDRATE;
D O I：
10.1107/S1600536812001493
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, (C5H7N2)[Fe(C7H3NO4)(2)] or [2-apyH][Fe(pydc)(2)], the asymmetric unit contains an [Fe(pydc)(2)](-) (pydc is pyridine-2,6-dicarboxylate) anion and a protonated 2-aminopyridine cation ([2-apyH](+)). The complex anion contains an Fe-III atom within a distorted octahedral FeN2O4 coordination geometry. N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonding, offset pi-pi stacking [centroid-centroid distance = 3.805 (13) angstrom] and C-O center dot center dot center dot pi interactions [3.494 (14) angstrom] generate a three-dimensional network structure.
引用
收藏
页码：M174 / U872
页数：11
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