Synthesis of 12-aryl-8,9,10,12-tetrahydrobenzo[a]xanthene-11-ones catalyzed by biodegradable ionic liquid

被引：15

作者：

Fang, Dong ^{[1
]}

Yang, Jin-ming ^{[1
]}

Cao, Yan-fang ^{[1
]}

机构：

[1] Yancheng Normal Univ, Dept Pharmaceut Engn, Yancheng 224002, Jiangsu, Peoples R China

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2013年 / 39卷 / 04期

关键词：

Xanthene; Synthesis; Biodegradable ionic liquid; Solvent-free; Multi-component reaction; ONE-POT SYNTHESIS; SOLVENT-FREE SYNTHESIS; XANTHENE; DERIVATIVES; MULTICOMPONENT; TRIFLATE; DYES;

D O I：

10.1007/s11164-012-0709-4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A biodegradable acyclic SO3H-functionalized ionic liquid has been used as a novel catalyst for the synthesis of 12-aryl-8,9,10,12-tetrahydrobenzo[a]xanthene-11-ones via one-pot multi-component condensation of beta-naphthol, aromatic aldehydes, and cyclic 1,3-dicarbonyl compounds, under solvent-free conditions, to afford good to excellent yields ranging from 85 to 93 % within 30-60 min. After the reaction the products could be simply separated from the reaction mixture and the catalyst could be recycled and reused several times without noticeable reduction of catalytic activity.

引用

页码：1745 / 1751

页数：7

共 50 条

[41] Methanesulfonic Acid-Catalyzed One-Pot Synthesis of 12-Aryl or 12-Alkyl-8,9,10,12-tetrahydrobenzo[a]xanthen-11-one Derivatives
Liu, Yu-Heng
Li, Lei
JOURNAL OF HETEROCYCLIC CHEMISTRY, 2012, 49 (04) : 861 - 864
[42] Efficient One-pot Synthesis of 12-Aryl-8,9,10, 12-Tetrahydrobenzo[a]xanthen-11-ones Catalyzed by CuO-CeO2 Nanocomposite Under Solvent-free Conditions
Tavakoli, Ziba
Albadi, Jalal
CHIANG MAI JOURNAL OF SCIENCE, 2017, 44 (04): : 1497 - 1503
[43] Cu(II) Anchored on Modified Magnetic Nanoparticles: As a Green and Efficient Recyclable Nano Catalyst for One Pot Synthesis of 12-Aryl-8,9,10,12tetrahydrobenzo[a]xanthene-11-one"
Sonei, Samin
Gholizadeh, Mostafa
Taghavi, Faezeh
POLYCYCLIC AROMATIC COMPOUNDS, 2020, 40 (04) : 1127 - 1142
[44] Ultrasound assisted synthesis of tetrahydrobenzo[c]xanthene-11-ones using CAN as catalyst
Sudha, S.
Pasha, M. A.
ULTRASONICS SONOCHEMISTRY, 2012, 19 (05) : 994 - 998
[45] Synthesis, Characterization, in silico Molecular Docking and Antibacterial Properties of Some Tetrahydrobenzo[a]xanthene-11-ones
Mennana, Imene
Nemouchi, Sara
Sehout, Imene
Krid, Adel
Boulcina, Raouf
Mechouche, Meroua Safa
Debache, Abdelmajid
ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 2024, 56 (04) : 379 - 391
[46] Synthesis, NMR spectral, docking and antimicrobial studies of some 12-aryl-9,9-dimethyl-8,9,10,12-tetrahydrobenzo[a]xanthen-11-one tosylhydrazones
Sathiya, C.
Anand, P. Surendar
Sethukumar, A.
Kumar, C. Udhaya
Kumar, T. V. Ajay
Senthan, S.
Prakasam, B. Arul
JOURNAL OF MOLECULAR STRUCTURE, 2022, 1254
[47] Iodine-Catalyzed Synthesis of 12-Aryl-8,9,10,12-tetrahydro-benzo[a]xanthen-11-one Derivatives via Multicomponent Reaction
Wang, Rui-Zhi
Zhang, Li-Feng
Cui, Zhen-Shui
SYNTHETIC COMMUNICATIONS, 2009, 39 (12) : 2101 - 2107
[48] Synthesis and spectral studies on some tetrahydrobenzoxanthen-11-ones: crystal and molecular structure of 9,9-dimethyl-12-(2-nitrophenyl)-8,9,10,12-tetrahydrobenzo[a]xanthen-11-one
A. Sethukumar
Millet M. Chandy
B. Arul Prakasam
Raghavaiah Pallepogu
Structural Chemistry, 2011, 22 : 671 - 680
[49] Synthesis of SCMNPs@imine/SO3H magnetic nanocatalyst by chlorosulfonic acid as sulfonating agents and their application for the preparation of 12-aryl-8,9,10,12-tetrahydrobenzo[a]xanthen-11-one and 1,8-dioxooctahydroxanthene derivatives
Zhou, Ji
Liu, Dan
Wu, Fengshou
Xiong, Yun
Ashraf, Muhammad Aqeel
MATERIALS RESEARCH EXPRESS, 2020, 7 (01)
[50] Synthesis and spectral studies on some tetrahydrobenzoxanthen-11-ones: crystal and molecular structure of 9,9-dimethyl-12-(2-nitrophenyl)-8,9,10,12-tetrahydrobenzo[a]xanthen-11-one
Sethukumar, A.
Chandy, Millet M.
Prakasam, B. Arul
Pallepogu, Raghavaiah
STRUCTURAL CHEMISTRY, 2011, 22 (03) : 671 - 680

← 1 2 3 4 5 →